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The effect of reversing current deposition on the apparent density of electrolytic copper powder / Uticaj reversne struje na nasipnu masu pri elektrolitičkom taloženju bakarnog praha
(Serbian Chemical Society, 2002)
The possibility of depositing copper powders with different apparent density by changing the shape of reversing current wave is shown. The morphology and crystallinity of powder particles can be varied considerably by ...
Intramolecular Barbier reaction in water: Cyclopentane and cyclohexane ring closure / Intramolekulska Barbier-ova reakcija u vodi - sinteza petočlanih i šestočlanih prstenova
(Serbian Chemical Society, 2002)
Zinc or indium promoted intramolecular Barbier reactions of aldehydes containing a suitably positioned allylic or propargylic halide unit afford unsaturated cyclic alcohols in moderate yields.
Regioselectivity of conjugate additions to monoalkyl-1,4-benzoquinones / Regioselektivnost konjugovane adicijena monoalkil-1,4-benzohinone
(Serbian Chemical Society, 2002)
The regioselectivity of the reaction of conjugate addition of thiols amines, methanol and hydrogen chloride with the monoalkyl-1,4-benzoquinones avarone and 2-tert-butyl- 1,4-benzoquinone was investigated. It was shown ...
An estimation of the interfacial energy of the copper-copper sulphate solution interface and of the specific surface of copper powder / Procena međupovršinske energije bakar-rastvor bakar sulfata i specifične površine bakarnog praha
(Serbian Chemical Society, 2002)
Apossible way for the estimation of the interfacial energy of the copper – copper sulphate solution interface is proposed. The estimated value of (2.7±0.3) J cm-2 and the derived equations which relate the specific surface ...
Study of sepiolite from Goles (Kosovo, Yugoslavia). I. Sorption capacity
(Serbian Chemical Society, 2002)
The sorption of molecules of different size and polarity (water. n-hexane. isooctane, benzene. toluene, cyclohexane, carbon tetrachloride, isopropanol, isobutanol, methanol, ethanol) by sepiolite from Gores. i.e. from the ...
A model study of epothilone synthesis: An alternative synthetic approach to the C1-C7 fragment / Model studija u sintezi epotilona - alternativni pristup sintezi C1-C7 fragmenta
(Serbian Chemical Society, 2002)
In this model study an alternative synthetic approach to the C1–C7 fragment of epothilones was investigated. Starting from 4,4-dimethylcyclopentenone, a 7 step reaction sequence afforded the key intermediate 7 in 27% overall ...
Antimalarial peroxides: The first intramolecular 1,2,4,5-tetraoxane / Antimalarijski peroksidi - prvi intramolekulski 1,2,4,5-tetraoksan
(Serbian Chemical Society, 2002)
An intramolecular steroidal 1,2,4,5-tetraoxane has been synthesised in six steps starting from methyl3-oxo-7α,12α-diacetoxy-5β-cholan-24-oate. The synthesised 1,2,4,5-tetraoxane has moderate in vitro antimalarial activity ...
An optimized synthesis of a key pharmaceutical intermediate methyl 4-[(1-oxopropyl)phenylamino]piperidine-4-carboxylate / Optimizovana sinteza značajnog farmaceutskog intermedijera metil 4-[(1-oksopropil)fenilamino]piperidin-4-karboksilata
(Serbian Chemical Soc, Belgrade, 2002)
An efficient synthesis of methyl 4-[(1-oxopropyl)phenylamino]piperidine-4-carboxylate (7) has been developed, starting from 1-benzylpiperidin-4-one (1), The compound is a key intermediate in the synthesis of new generation, ...
Hydride reduction of B-norcholestane 5α,6α-epoxide / Hidridna redukcija B-norholestan 5α,6α-epoksida
(Serbian Chemical Society, 2002)
B-Norcholestane epoxide 2 is reduced with lithium aluminium hydride to give either the 3β,6α-diol 3 or the corresponding 3β,5α-diol 4, depending on the quality of the reducing reagent employed. Aplausible mechanistic ...
Reflection and structural characteristics of semi-bright and mirror bright nickel coatings / Refleksione i strukturne karakteristike polusjajnih i ogledalski sjajnih prevlaka nikla
(Serbian Chemical Society, 2002)
The reflection and structural characteristics of the nickel coatings obtained in the presence of a basic brightening addition agent only, and of both a basic and top brightening addition agent are examined. It is shown ...