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Intramolecular Barbier reaction in water: Cyclopentane and cyclohexane ring closure

Intramolekulska Barbier-ova reakcija u vodi - sinteza petočlanih i šestočlanih prstenova

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2002
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Authors
Ivković, Aleksandar
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
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Abstract
Zinc or indium promoted intramolecular Barbier reactions of aldehydes containing a suitably positioned allylic or propargylic halide unit afford unsaturated cyclic alcohols in moderate yields.
Aldehidi koji u pogodnom položaju poseduju alil-halogenidnu ili propargil halogenidnu strukturnu jedinicu reaguju u vodenim uslovima sa cinkom ili indijumom, pri čemu nastaju nezasićeni ciklični alkoholi u umerenim prinosima.
Keywords:
Barbier reactions / cyclisation / allylation / allenes / zinc / indium
Source:
Journal of the Serbian Chemical Society, 2002, 67, 3, 141-148
Publisher:
  • Serbian Chemical Society

DOI: 10.2298/JSC0203141I

ISSN: 0352-5139

WoS: 000174611800001

Scopus: 2-s2.0-0036003611
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/81
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