B-Norcholestane epoxide 2 is reduced with lithium aluminium hydride to give either the 3β,6α-diol 3 or the corresponding 3β,5α-diol 4, depending on the quality of the reducing reagent employed. Aplausible mechanistic explanation of the obtained results is suggested.
Redukcijom B-norholestan-epoksida 2 pomoću litijum-aluminijum-hidrida dobijeni su odgovarajući 3β,6α-diol 3 ili 3β,5α-diol 4, u zavisnosti od kvaliteta upotrebljenog redukcionog reagensa. Predloženo je verovatno mehanističko tumačenje dobijenih rezultata.
TY - JOUR
AU - Bjelaković, Mira
AU - Pavlović, Vladimir D.
AU - Lorenc, Ljubinka
PY - 2002
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/60
AB - B-Norcholestane epoxide 2 is reduced with lithium aluminium hydride to give either the 3β,6α-diol 3 or the corresponding 3β,5α-diol 4, depending on the quality of the reducing reagent employed. Aplausible mechanistic explanation of the obtained results is suggested.
AB - Redukcijom B-norholestan-epoksida 2 pomoću litijum-aluminijum-hidrida dobijeni su odgovarajući 3β,6α-diol 3 ili 3β,5α-diol 4, u zavisnosti od kvaliteta upotrebljenog redukcionog reagensa. Predloženo je verovatno mehanističko tumačenje dobijenih rezultata.
PB - Serbian Chemical Society
T2 - Journal of the Serbian Chemical Society
T1 - Hydride reduction of B-norcholestane 5α,6α-epoxide
T1 - Hidridna redukcija B-norholestan 5α,6α-epoksida
VL - 67
IS - 2
SP - 69
EP - 75
DO - 10.2298/JSC0202069B
ER -
@article{
author = "Bjelaković, Mira and Pavlović, Vladimir D. and Lorenc, Ljubinka",
year = "2002",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/60",
abstract = "B-Norcholestane epoxide 2 is reduced with lithium aluminium hydride to give either the 3β,6α-diol 3 or the corresponding 3β,5α-diol 4, depending on the quality of the reducing reagent employed. Aplausible mechanistic explanation of the obtained results is suggested., Redukcijom B-norholestan-epoksida 2 pomoću litijum-aluminijum-hidrida dobijeni su odgovarajući 3β,6α-diol 3 ili 3β,5α-diol 4, u zavisnosti od kvaliteta upotrebljenog redukcionog reagensa. Predloženo je verovatno mehanističko tumačenje dobijenih rezultata.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Hydride reduction of B-norcholestane 5α,6α-epoxide, Hidridna redukcija B-norholestan 5α,6α-epoksida",
volume = "67",
number = "2",
pages = "69-75",
doi = "10.2298/JSC0202069B"
}
Bjelaković, M., Pavlović, V. D.,& Lorenc, L. (2002). Hidridna redukcija B-norholestan 5α,6α-epoksida.
Journal of the Serbian Chemical Society
Serbian Chemical Society., 67(2), 69-75.
https://doi.org/10.2298/JSC0202069B
Bjelaković M, Pavlović VD, Lorenc L. Hidridna redukcija B-norholestan 5α,6α-epoksida. Journal of the Serbian Chemical Society. 2002;67(2):69-75
Bjelaković Mira, Pavlović Vladimir D., Lorenc Ljubinka, "Hidridna redukcija B-norholestan 5α,6α-epoksida" Journal of the Serbian Chemical Society, 67, no. 2 (2002):69-75,
https://doi.org/10.2298/JSC0202069B .
