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Thermodynamics of hydrolysis of cellulose to glucose from 0 to 100 °C: Cellulosic biofuel applications and climate change implications
(Elsevier, 2018)
Hydrolysis of cellulose to glucose is a key reaction in renewable energy from biomass and in mineralization of soil organic matter to CO2. Conditional thermodynamic parameters, ΔhydG’, ΔhydH’, and ΔhydS’, and equilibrium ...
Chemical modification of chloroperoxidase for enhanced stability and activity
(Elsevier Sci Ltd, Oxford, 2014)
Chloroperoxidase from Caldariomyces fumago (CPO, EC 1.11.1.10) is one of the most interesting enzymes from the group of heme peroxidases and has been extensively applied in synthetic processes. Nevertheless, the practical ...
High performance alkyd resins synthesized from postconsumer PET bottles
(The Royal Society of Chemistry, 2015)
The glycolytic recycling of waste PET presents a challenge for the production of secondary value-added products, such as alkyd resins. A way to overcome the unsatisfactory mechanical, drying and chemical resistance properties ...
Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid
(American Chemical Society (ACS), 2017)
For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in ...
Laws of evolution parallel the laws of thermodynamics
(Elsevier, 2018)
We hypothesize that concepts from thermodynamics and statistical mechanics can be used to define summary statistics, similar to thermodynamic entropy, to summarize the convergence of processes driven by random inputs subject ...
TiO2/WO3 photocatalytic composite coatings prepared by spray pyrolysis
(Elsevier, 2014)
TiO2/WO3 composites supported on a stainless steel foil were prepared by the spray pyrolysis technique. Content of WO3 was gradually increased from 1 wt% to 100 wt.%, while the coating thickness was limited to about 1 pm. ...
Phycocyanobilin, a bioactive tetrapyrrolic compound of blue-green alga Spirulina, binds with high affinity and competes with bilirubin for binding on human serum albumin
(Royal Soc Chemistry, Cambridge, 2015)
Human serum albumin (HSA) is an important regulator of the pharmacokinetic properties of bioactive compounds. Phycocyanobilin is a blue tetrapyrrole chromophore of C-phycocyanin with proven health-promoting activities. ...
Lipophilicity Assessment of Ruthenium(II)-Arene Complexes by the Means of Reversed-Phase Thin-Layer Chromatography and DFT Calculations
(Hindawi Publishing Corporation, New York, 2014)
The lipophilicity of ten ruthenium(II)-arene complexes was assessed by reversed-phase thin-layer chromatography (RP-TLC) on octadecyl silica stationary phase. The binary solvent systems composed of water and acetonitrile ...
Influence of peanut matrix on stability of allergens in gastric-simulated digesta: 2S albumins are main contributors to the IgE reactivity of short digestion-resistant peptides
(Wiley, Hoboken, 2018)
BackgroundMost food allergens sensitizing via the gastrointestinal tract are stable proteins that are resistant to pepsin digestion, in particular major peanut allergens, Ara h 2 and Ara h 6. Survival of their large fragments ...