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Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone
(Elsevier, 1967)
Reaction mechanism of diazoketone photolysie is assumed
to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and
reaction medium. Numerous example8 of ...
The structure of glycerol acetals
(Elsevier, 1967)
It is known that the condensation of with polyols yields cyclic acetals. Thus, carbonyl compounds it is known that by condensation of benzaldehyde with glycerol, a mixture of 2-phenyl-5-hydroxy-1,3-dioxane and 2-phenyl-4 ...
Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process
(IOP Publishing, 1969)
The cathode process of hydrogen evolution in chlorate cells, including possible depolarization, has not been studied to date. High hydrogen polarization at graphite electrodes delayed the industrial application of bipolar ...
Investigation of active carbon for fuel-cell electrodes
(Elsevier, 1969)
The influence of grain size, mode of catalyst impregnation, and different surface treatments on the electrochemical activity of active carbon for hydrogen fuel-cell electrodes was studied. The experiments were done in a ...
Opening of steroid ring a by means of lead tetraacetate
(Elsevier, 1964)
The lead tetraacetate oxidation of cholestan-1β-ol and cholestan-1α-ol in benzene solution did not afford cyclic ethers but resulted, in major part, in the opening of ring A with formation of 1,10-seco-aldehydes. In addition, ...
Studies on Chlorate Cell Process IV. Effect of Neutral Salts on Conversion of Available Chlorine to Chlorate
(IOP Publishing, 1969)
It has been shown that neutral salts, such as Nacl and and Naclo3 and their mixtures, cause an apparent increase in the thermodynamic dissociation constants of weak acids and bases. The pH value of aqueous salt solutions ...
Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight
(Elsevier, 1965)
The action of lead tetraacetate on ethanol, 1-propanol, 2-propanol and 2-butanol has been studied under various experimental conditions, and it was found that the tetravalent lead compound reacts with alcohols in ways not ...
Study of the reactions of hexanitrocobaltates(III) with amino acids. II. Determination of the configuration of dinitrobis(glycinato)cobaltate(III) ions
(USA : American Chemical Society, 1965)
In a previously published paper1 we have undertaken
a study of the reactions of hexanitrocobaltate(III)
with amino acids. The first reaction we studied was
that of glycine with potassium and sodium hexanitrocobaltate(
III). ...
Studies on Chlorate Cell Process: V . Theory and Practice of a Modified Technology for Electrolytic Chlorate Production
(IOP Publishing, 1969)
A modified technology for electrolytic chlorate production has been developed.
The cell is considered as a hypochlorite generator and the holding
volume as a reactor for the conversion of available chlorine to chlorate. ...
Lead tetraacetate oxidation of saturated aliphatic alcohols.-III. Unbranched primary and secondary alcohols
(Elsevier, 1965)
The action of lead tetraacetate, in benzene solution, on various unbranched primary and secondary aliphatic alcohols containing 4 to 12 carbon atoms has been investigated and the ratio of carbonyl compounds, cyclic ethers ...