The action of lead tetraacetate on ethanol, 1-propanol, 2-propanol and 2-butanol has been studied under various experimental conditions, and it was found that the tetravalent lead compound reacts with alcohols in ways not so far observed. The possible reaction schemes are discussed in terms of homolytic and heterolytic cleavage of the intermediate alkoxy lead acetate complexes.
Keywords:
lead tetraacetate-IV / ethanol / 1-propanol / 2-propanol / 2-butanol / tetravalent lead compound
TY - JOUR
AU - Mihailović, Milhailo Lj.
AU - Maksimović, Z.
AU - Jeremić, Dragoslav
AU - Čeković, Živorad M.
AU - Milovanović, Aleksandar Ž.
AU - Lorenc, Ljubinka B.
PY - 1965
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4542
AB - The action of lead tetraacetate on ethanol, 1-propanol, 2-propanol and 2-butanol has been studied under various experimental conditions, and it was found that the tetravalent lead compound reacts with alcohols in ways not so far observed. The possible reaction schemes are discussed in terms of homolytic and heterolytic cleavage of the intermediate alkoxy lead acetate complexes.
PB - Elsevier
T2 - Tetrahedron
T1 - Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight
VL - 21
IS - 6
SP - 1395
EP - 1410
DO - 10.1016/S0040-4020(01)98301-2
ER -
@article{
author = "Mihailović, Milhailo Lj. and Maksimović, Z. and Jeremić, Dragoslav and Čeković, Živorad M. and Milovanović, Aleksandar Ž. and Lorenc, Ljubinka B.",
year = "1965",
abstract = "The action of lead tetraacetate on ethanol, 1-propanol, 2-propanol and 2-butanol has been studied under various experimental conditions, and it was found that the tetravalent lead compound reacts with alcohols in ways not so far observed. The possible reaction schemes are discussed in terms of homolytic and heterolytic cleavage of the intermediate alkoxy lead acetate complexes.",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight",
volume = "21",
number = "6",
pages = "1395-1410",
doi = "10.1016/S0040-4020(01)98301-2"
}
Mihailović, M. Lj., Maksimović, Z., Jeremić, D., Čeković, Ž. M., Milovanović, A. Ž.,& Lorenc, L. B.. (1965). Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight. in Tetrahedron
Elsevier., 21(6), 1395-1410.
https://doi.org/10.1016/S0040-4020(01)98301-2
Mihailović ML, Maksimović Z, Jeremić D, Čeković ŽM, Milovanović AŽ, Lorenc LB. Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight. in Tetrahedron. 1965;21(6):1395-1410.
doi:10.1016/S0040-4020(01)98301-2 .
Mihailović, Milhailo Lj., Maksimović, Z., Jeremić, Dragoslav, Čeković, Živorad M., Milovanović, Aleksandar Ž., Lorenc, Ljubinka B., "Reactions with lead tetraacetate-IV. Oxidation of saturated aliphatic alcohols-II; Alcohols of low molecular weight" in Tetrahedron, 21, no. 6 (1965):1395-1410,
https://doi.org/10.1016/S0040-4020(01)98301-2 . .
