The lead tetraacetate oxidation of cholestan-1β-ol and cholestan-1α-ol in benzene solution did not afford cyclic ethers but resulted, in major part, in the opening of ring A with formation of 1,10-seco-aldehydes. In addition, cholestane, cholest-1-ene and cholestan-1-one were also obtained.
Keywords:
steroid ring / lead tetraacetate / cyclic ethers / cholestane / cholest-1-ene / cholestan-1-one
TY - JOUR
AU - Stefanović, Milutin
AU - Gašić, Miroslav I.
AU - Lorenc, Ljubinka B.
AU - Mihailović, Milhailo Lj.
PY - 1964
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4538
AB - The lead tetraacetate oxidation of cholestan-1β-ol and cholestan-1α-ol in benzene solution did not afford cyclic ethers but resulted, in major part, in the opening of ring A with formation of 1,10-seco-aldehydes. In addition, cholestane, cholest-1-ene and cholestan-1-one were also obtained.
PB - Elsevier
T2 - Tetrahedron
T1 - Opening of steroid ring a by means of lead tetraacetate
VL - 20
IS - 10
SP - 2289
EP - 2294
DO - 10.1016/S0040-4020(01)97616-1
ER -
@article{
author = "Stefanović, Milutin and Gašić, Miroslav I. and Lorenc, Ljubinka B. and Mihailović, Milhailo Lj.",
year = "1964",
abstract = "The lead tetraacetate oxidation of cholestan-1β-ol and cholestan-1α-ol in benzene solution did not afford cyclic ethers but resulted, in major part, in the opening of ring A with formation of 1,10-seco-aldehydes. In addition, cholestane, cholest-1-ene and cholestan-1-one were also obtained.",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "Opening of steroid ring a by means of lead tetraacetate",
volume = "20",
number = "10",
pages = "2289-2294",
doi = "10.1016/S0040-4020(01)97616-1"
}
Stefanović, M., Gašić, M. I., Lorenc, L. B.,& Mihailović, M. Lj.. (1964). Opening of steroid ring a by means of lead tetraacetate. in Tetrahedron
Elsevier., 20(10), 2289-2294.
https://doi.org/10.1016/S0040-4020(01)97616-1
Stefanović M, Gašić MI, Lorenc LB, Mihailović ML. Opening of steroid ring a by means of lead tetraacetate. in Tetrahedron. 1964;20(10):2289-2294.
doi:10.1016/S0040-4020(01)97616-1 .
Stefanović, Milutin, Gašić, Miroslav I., Lorenc, Ljubinka B., Mihailović, Milhailo Lj., "Opening of steroid ring a by means of lead tetraacetate" in Tetrahedron, 20, no. 10 (1964):2289-2294,
https://doi.org/10.1016/S0040-4020(01)97616-1 . .
