Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone

Tasovac, R.; Stefanović, Milutin; Stojiljković, A.

doi:10.1016/S0040-4039(01)89983-4

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1967

Authors

Tasovac, R.
Stefanović, Milutin
Stojiljković, A.

Article (Published version)

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Abstract

Reaction mechanism of diazoketone photolysie is assumed to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and reaction medium. Numerous example8 of Wolff-rearrangement (1) 1,2-hydrogen shift (2) and intermolecular reactions (3) are available.

Keywords:

photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert / Butylcyclohexanone / photolysie / molecular structure / hydrogen / intermolecular reaction

Source:
Tetrahedron Letters, 1967, 8, 28, 2729-2732

Publisher:

Elsevier

DOI: 10.1016/S0040-4039(01)89983-4

ISSN: 0040-4039; 1873-3581

Scopus: 2-s2.0-0005760829

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	6

TY  - JOUR
AU  - Tasovac, R.
AU  - Stefanović, Milutin
AU  - Stojiljković, A.
PY  - 1967
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4666
AB  - Reaction mechanism of diazoketone photolysie is assumed 
to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and 
reaction medium. Numerous example8 of Wolff-rearrangement (1) 
1,2-hydrogen shift (2) and intermolecular reactions (3) are available.
PB  - Elsevier
T2  - Tetrahedron Letters
T1  - Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone
VL  - 8
IS  - 28
SP  - 2729
EP  - 2732
DO  - 10.1016/S0040-4039(01)89983-4
ER  -

@article{
author = "Tasovac, R. and Stefanović, Milutin and Stojiljković, A.",
year = "1967",
abstract = "Reaction mechanism of diazoketone photolysie is assumed 
to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and 
reaction medium. Numerous example8 of Wolff-rearrangement (1) 
1,2-hydrogen shift (2) and intermolecular reactions (3) are available.",
publisher = "Elsevier",
journal = "Tetrahedron Letters",
title = "Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone",
volume = "8",
number = "28",
pages = "2729-2732",
doi = "10.1016/S0040-4039(01)89983-4"
}

Tasovac, R., Stefanović, M.,& Stojiljković, A.. (1967). Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone. in Tetrahedron Letters
Elsevier., 8(28), 2729-2732.
https://doi.org/10.1016/S0040-4039(01)89983-4

Tasovac R, Stefanović M, Stojiljković A. Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone. in Tetrahedron Letters. 1967;8(28):2729-2732.
doi:10.1016/S0040-4039(01)89983-4 .

Tasovac, R., Stefanović, Milutin, Stojiljković, A., "Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone" in Tetrahedron Letters, 8, no. 28 (1967):2729-2732,
https://doi.org/10.1016/S0040-4039(01)89983-4 . .