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Lead tetra-acetate oxidation of saturated aliphatic alcohols-V. Factors influencing the formation of cyclic ethers and carbonyl compounds
(Elsevier, 1966)
Factors influencing the relative rates of the homolytic and heterolytic processes in the lead tetra-acetate oxidation of unbranched primary and secondary aliphatic alcohols have been investigated, with a view to determine ...
Reactions with lead tetraacetate. I. Oxidation of saturated aliphatic alcohols. Part 1
(Elsevier, 1963)
It was recently shown that various steroid alcohols could react with lead tetraacetate in non-polar solvents to give tetrahydrofuran and tetrahydropyran derivatives. cyclization occurring when the position of and the ...
The conversion of unbranched primary alkyl and arylalkyl amines to nitriles by means of lead tetraacetate
(Elsevier, 1965)
The only amino compounds oxidized so far with lead tetroacetate were primary aromatic amines, which gave mainly the corresponding azo compounds(1), and some tertiary aryldialkyl amines, which in glacial acetic acid in the ...
Study of the reaction of hexanitrocobaltates(III) with amino acids. IV. The reations with DL-alanine, D-alanine, L-alanine, and β-alanine
(Elsevier, 1968)
The reactions of alkali hexanitrocobaltates(III) with DL-alanine, D-alanine, L-alanine, and β-alanine have been investigated. Thereby new classes of alkali dinitro-bis (aminoacido)cobaltates(III), M[CoAm2(NO2)2] were ...
A proposal for use of "Tandel" to obtain optimal temperature of electro-optical devices
(Elsevier, 1966)
A proposal is given for the use of Tandel to obtain the desirable temperature of ferroelectric crystal and optimal working temperature of electro-optical devices as well. The variation of ∈ due to temperature inhomogeneity ...
The reaction of lead tetra-acetate with some acyclic hydroxy-ethers
(Elsevier, 1966)
By means of lead tetra-acetate in refluxing benzene open-chain 1,2-, 1,3-, 1,4- and 1,5-hydroxy-ethers are mainly converted to the corresponding five-membered or six-membered cylic products. Thus, 2-alkoxy-1-ethanols afford ...
Selective borane reductions of progesterone
(Elsevier, 1967)
A number of selective reductions using borane end metal borohydrides has been described. In our studies of hydroboration of steroid conjugated ketones under different conditions and with different solvents we have found ...
An improved preparation of 3-α-acetoxy-11,20-diketo-(5β)-pregnane, the key intermediate in the synthesis of 11-oxygenated corticosteroids
(Elsevier, 1967)
Although microbiological methods of introducing oxygen at C-11 of the steroid molecule are effective, it is obvious that purely synthetic way of producing cortisone and its analogs from bile acids or hecogenin have never ...
Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids
(Elsevier, 1966)
Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied ...
Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone
(Elsevier, 1967)
Reaction mechanism of diazoketone photolysie is assumed
to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and
reaction medium. Numerous example8 of ...