The reaction of lead tetra-acetate with some acyclic hydroxy-ethers
Само за регистроване кориснике
1966
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
By means of lead tetra-acetate in refluxing benzene open-chain 1,2-, 1,3-, 1,4- and 1,5-hydroxy-ethers are mainly converted to the corresponding five-membered or six-membered cylic products. Thus, 2-alkoxy-1-ethanols afford 2-substituted 1,3-dioxolanes in 50-53% yield and 4-ethoxy-1-butanol gives 2-ethoxytetrahydrofuran in 52% yield; 3-alkoxy-1-propanols are oxidized to the corresponding 2-substituted 1,3-dioxans in 26-40% yield and 5-ethoxy-1-pentanol cyclizes to 2-ethoxytetrahydropyran in 46% yield. 2-Phenoxyethanol undergoes ring closure to 1,4-benzodioxan in 15% yield.
Кључне речи:
acyclic hydroxy-ethers / lead tetra-acetate / synthesis / ring closure / cyclisationИзвор:
Tetrahedron, 1966, 22, 2, 723-738Издавач:
- Elsevier
Финансирање / пројекти:
- The Serbian Republic Research Fund
- The Yugoslav Federal Research Fund
Институција/група
IHTMTY - JOUR AU - Mihailović, Milhailo Lj. AU - Miloradović, M. PY - 1966 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4685 AB - By means of lead tetra-acetate in refluxing benzene open-chain 1,2-, 1,3-, 1,4- and 1,5-hydroxy-ethers are mainly converted to the corresponding five-membered or six-membered cylic products. Thus, 2-alkoxy-1-ethanols afford 2-substituted 1,3-dioxolanes in 50-53% yield and 4-ethoxy-1-butanol gives 2-ethoxytetrahydrofuran in 52% yield; 3-alkoxy-1-propanols are oxidized to the corresponding 2-substituted 1,3-dioxans in 26-40% yield and 5-ethoxy-1-pentanol cyclizes to 2-ethoxytetrahydropyran in 46% yield. 2-Phenoxyethanol undergoes ring closure to 1,4-benzodioxan in 15% yield. PB - Elsevier T2 - Tetrahedron T1 - The reaction of lead tetra-acetate with some acyclic hydroxy-ethers VL - 22 IS - 2 SP - 723 EP - 738 DO - 10.1016/0040-4020(66)80043-1 ER -
@article{ author = "Mihailović, Milhailo Lj. and Miloradović, M.", year = "1966", abstract = "By means of lead tetra-acetate in refluxing benzene open-chain 1,2-, 1,3-, 1,4- and 1,5-hydroxy-ethers are mainly converted to the corresponding five-membered or six-membered cylic products. Thus, 2-alkoxy-1-ethanols afford 2-substituted 1,3-dioxolanes in 50-53% yield and 4-ethoxy-1-butanol gives 2-ethoxytetrahydrofuran in 52% yield; 3-alkoxy-1-propanols are oxidized to the corresponding 2-substituted 1,3-dioxans in 26-40% yield and 5-ethoxy-1-pentanol cyclizes to 2-ethoxytetrahydropyran in 46% yield. 2-Phenoxyethanol undergoes ring closure to 1,4-benzodioxan in 15% yield.", publisher = "Elsevier", journal = "Tetrahedron", title = "The reaction of lead tetra-acetate with some acyclic hydroxy-ethers", volume = "22", number = "2", pages = "723-738", doi = "10.1016/0040-4020(66)80043-1" }
Mihailović, M. Lj.,& Miloradović, M.. (1966). The reaction of lead tetra-acetate with some acyclic hydroxy-ethers. in Tetrahedron Elsevier., 22(2), 723-738. https://doi.org/10.1016/0040-4020(66)80043-1
Mihailović ML, Miloradović M. The reaction of lead tetra-acetate with some acyclic hydroxy-ethers. in Tetrahedron. 1966;22(2):723-738. doi:10.1016/0040-4020(66)80043-1 .
Mihailović, Milhailo Lj., Miloradović, M., "The reaction of lead tetra-acetate with some acyclic hydroxy-ethers" in Tetrahedron, 22, no. 2 (1966):723-738, https://doi.org/10.1016/0040-4020(66)80043-1 . .