Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations
TY - JOUR
AU - Mihailović, Mihailo
AU - Lorenc, Ljubinka
AU - Gašić, Miroslav J.
AU - Rogić, Milorad
AU - Melera, A.
AU - Stefanović, Milutin
PY - 1966
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4161
AB - Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations
PB - Elsevier
T2 - Tetrahedron
T1 - Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids
VL - 22
IS - 7
SP - 2345
EP - 2358
DO - 10.1016/S0040-4020(01)82154-2
ER -
@article{
author = "Mihailović, Mihailo and Lorenc, Ljubinka and Gašić, Miroslav J. and Rogić, Milorad and Melera, A. and Stefanović, Milutin",
year = "1966",
url = "https://cer.ihtm.bg.ac.rs/handle/123456789/4161",
abstract = "Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids",
volume = "22",
number = "7",
pages = "2345-2358",
doi = "10.1016/S0040-4020(01)82154-2"
}
Mihailović, M., Lorenc, L., Gašić, M. J., Rogić, M., Melera, A.,& Stefanović, M. (1966). Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids.
Tetrahedron
Elsevier., 22(7), 2345-2358.
https://doi.org/10.1016/S0040-4020(01)82154-2
Mihailović M, Lorenc L, Gašić MJ, Rogić M, Melera A, Stefanović M. Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids. Tetrahedron. 1966;22(7):2345-2358
Mihailović Mihailo, Lorenc Ljubinka, Gašić Miroslav J., Rogić Milorad, Melera A., Stefanović Milutin, "Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids" Tetrahedron, 22, no. 7 (1966):2345-2358,
https://doi.org/10.1016/S0040-4020(01)82154-2 .
