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Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
Reflectance study of cation adsorption on oxide layers of gold and platinum electrodes
(Elsevier Sequoia S.A., Lausanne, 1979)
Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...
Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes
(Elsevier, 1976)
There have been several attempts to elucidate events occurring on platinum immersed into pure perchloric acid solutions, when submitted to high anodic polarisation. The polarisation curve was shown to exhibit two levels, ...
Electrochemical oxidation of formic acid at noble metals: Catalytic effects of foreign metal monolayers
(Elsevier, 1977)
The catalytic effects of a submonolayer of lead on noble metals have been shown and discussed in terms of a previously published model. A theoretical analysis of these effects is presented. It was demonstrated that foreign ...
Molybdenum and hydroxybenzene complexes in concentrated sulphuric acid
(Elsevier, 1976)
It is already known [1--5] that Ti, W, V, Mo and some other metals form
coloured complexes with 1,4-benzenediol in concentrated sulphuric acid. We
have also found that hydroxybenzene has similar properties. Papers found ...
The effect of faradaic processes on the resonance of electrochemical cells
(Elsevier, 1976)
Electrolytic cells consisting of mercury electrodes immersed into pure aqueous sulphuric acid solution (ideally polarizable electrodes) and in the one containing Ti3+/Ti4+ redox couple (presence of a faradaic process) were ...
Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...