It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.
TY - JOUR
AU - Adžić, Radoslav R.
AU - Simić, D. N.
AU - Despić, Aleksandar R.
AU - Dražić, Dragutin M.
PY - 1975
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4212
AB - It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.
PB - Elsevier
T2 - Journal of Electroanalytical Chemistry
T1 - Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum
VL - 65
IS - 2
SP - 587
EP - 601
DO - 10.1016/0368-1874(75)85146-X
ER -
@article{
author = "Adžić, Radoslav R. and Simić, D. N. and Despić, Aleksandar R. and Dražić, Dragutin M.",
year = "1975",
abstract = "It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum",
volume = "65",
number = "2",
pages = "587-601",
doi = "10.1016/0368-1874(75)85146-X"
}
Adžić, R. R., Simić, D. N., Despić, A. R.,& Dražić, D. M.. (1975). Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum. in Journal of Electroanalytical Chemistry
Elsevier., 65(2), 587-601.
https://doi.org/10.1016/0368-1874(75)85146-X
Adžić RR, Simić DN, Despić AR, Dražić DM. Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum. in Journal of Electroanalytical Chemistry. 1975;65(2):587-601.
doi:10.1016/0368-1874(75)85146-X .
Adžić, Radoslav R., Simić, D. N., Despić, Aleksandar R., Dražić, Dragutin M., "Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum" in Journal of Electroanalytical Chemistry, 65, no. 2 (1975):587-601,
https://doi.org/10.1016/0368-1874(75)85146-X . .
