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Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes

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1976
Authors
Nikolić, Branislav Ž.
Adžić, Radoslav A.
Despić, Aleksandar R.
Article (Published version)
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Abstract
There have been several attempts to elucidate events occurring on platinum immersed into pure perchloric acid solutions, when submitted to high anodic polarisation. The polarisation curve was shown to exhibit two levels, the second one occurring passed a limiting current which appears to be due to adsorption phenomena. Speculations have been made concerning the possible reaction mechanism which postulated the existence of several species acting as intermediates or reaction products. It was the purpose of this work to use some new techniques for the investigation of those species as well as to extend the observations to the alkaline perchlorate solutions and to those containing chlorate ions.
Keywords:
platinum / anodic processes on platinum / rotating double-ring electrodes / perchloric acid solution / chlorate ions / polarisation curve
Source:
Journal of Electroanalytical Chemistry, 1976, 72, 2, 251-256
Publisher:
  • Elsevier

DOI: 10.1016/S0022-0728(76)80174-X

ISSN: 0022-0728

Scopus: 2-s2.0-49549127259
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URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4700
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nikolić, Branislav Ž.
AU  - Adžić, Radoslav A.
AU  - Despić, Aleksandar R.
PY  - 1976
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4700
AB  - There have been several attempts to elucidate events occurring on platinum immersed into pure perchloric acid solutions, when submitted to high anodic polarisation. The polarisation curve was shown to exhibit two levels, the second one occurring passed a limiting current which appears to be due to adsorption phenomena. Speculations have been made concerning the possible reaction mechanism which postulated the existence of several species acting as intermediates or reaction products. It was the purpose of this work to use some new techniques for the investigation of those species as well as to extend the observations to the alkaline perchlorate solutions and to those containing chlorate ions.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes
VL  - 72
IS  - 2
SP  - 251
EP  - 256
DO  - 10.1016/S0022-0728(76)80174-X
ER  - 
@article{
author = "Nikolić, Branislav Ž. and Adžić, Radoslav A. and Despić, Aleksandar R.",
year = "1976",
abstract = "There have been several attempts to elucidate events occurring on platinum immersed into pure perchloric acid solutions, when submitted to high anodic polarisation. The polarisation curve was shown to exhibit two levels, the second one occurring passed a limiting current which appears to be due to adsorption phenomena. Speculations have been made concerning the possible reaction mechanism which postulated the existence of several species acting as intermediates or reaction products. It was the purpose of this work to use some new techniques for the investigation of those species as well as to extend the observations to the alkaline perchlorate solutions and to those containing chlorate ions.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes",
volume = "72",
number = "2",
pages = "251-256",
doi = "10.1016/S0022-0728(76)80174-X"
}
Nikolić, B. Ž., Adžić, R. A.,& Despić, A. R.. (1976). Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes. in Journal of Electroanalytical Chemistry
Elsevier., 72(2), 251-256.
https://doi.org/10.1016/S0022-0728(76)80174-X
Nikolić BŽ, Adžić RA, Despić AR. Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes. in Journal of Electroanalytical Chemistry. 1976;72(2):251-256.
doi:10.1016/S0022-0728(76)80174-X .
Nikolić, Branislav Ž., Adžić, Radoslav A., Despić, Aleksandar R., "Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes" in Journal of Electroanalytical Chemistry, 72, no. 2 (1976):251-256,
https://doi.org/10.1016/S0022-0728(76)80174-X . .

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