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Semisynthesis of Taxol (R): an improved procedure far the isolation of 10-deacetylbaccatin III
(Serbian Chemical Soc, Belgrade, 1999)
From the needles of domestic yew, (Taxus baccata), 10-deacetylbaccatin III (10-DAB) call be isolated in quantities of up to 297 mg per kg of fresh needles. Additional quantities of 10-DAB call be obtained from the extract ...
Free radical ring expansion and subsequent reactions of intermediary carbon radicals
(Serbian Chemical Society, 1996)
Alkyl radicals, derived from ethyl 1-(bromoalkyl)-2-oxocyclo-alkanecarboxylates or from the corresponding thiohydroxamic esters, undergo a ring expansion reaction and subsequent intermoleculaar addition/elimination reactions. ...
Organic geochemical study of the "W" oil-gas field in the Yugoslav part of the Pannonian basin
(Organic Geochemistry, 1990)
The naphthenic crude oil from the "W" oil-gas field differs from almost all other, paraffinic base oils discovered until now in the Yugoslav part of the Pannonian basin. In order to explain this difference, some geological ...
Covalent glycophospholipid binding to hemoglobin. A new post-translational modification occurring in erythrocytes exposed to insulin
(Serbian Chemical Society, 1996)
In this work a novel hitherto unrecognised hemoglobin (Hb) fraction, HbA1x, which we detected previously in hemolysates of erythrocytes exposed to high concentration of insulin under hypoglycemic conditions, both in vivo ...
An improved approach to B-norsteroids: An one-pot preparation of 3β-acetoxy-5-oxo-5,6-seco-cholestan-6-oic and 3β-acetoxy-5,17-dioxo-5,6-seco-androstan-6-oic acids
(Serbian Chemical Society, 1998)
A simple one-put procedure for the synthesis of the 5,6-seco-steroidal acids 9a,b in described in this paper. It consists of the epoxidation of the ▲ 5 -steroids, i.e., cholesteryl acetate (8a) and 17-oxo-aandrost-5-en-3β-yl ...
Sesquiterpene lactones from plant species Centaurea solstitialis L.
(Serbian Chemical Society, 1998)
The identification of nine known guaianolides, i.e., solstitialin A, its 13-acetate, linichlorin B, cynaropicrin, centaurepensin (chlorohyssopifolin A), 17-epi-centaurepensin, 19-desoxychlorojanerin, 11ß,13-dihydrodesacy ...
Synthesis of modified 5,10:8,14-bisfragmentation cholestane derivatives
(Serbian Chemical Society, 1996)
In this paper is described a synthetic pathway to the modified 5, 10:8, 14-bisfragmentation cholestene derivatives 10, 11 and 12, which involves introduction of the Δ8(14)-double bond and 5α-hydroxyl group in the cholestane ...
Synthesis and oxidative transformations of 5-hydroxy-5α-cholest-8-en-3β-yl acetate
(Serbian Chemical Society, 1997)
5-Hydroxy-5α-cholest-8-en-3β-yl acetate (8) (prepared in 6 steps starting from 7-dehydrocholesteryl acetate (1) was transformed with ruthenium tetroxide to 5-hydroxy-8,9-dioxo-8,9-seco-5α-cholestan-3β-yl acetate (9). ...
Stereoselective transformation of cyclodecene-1,4-dione systems, derived from steroids, to the corresponding spiro-g-lactones. A semiempirical MO Study
(MDPI, 1999)
The thermal and acid-catalyzed intramolecular rearrangement of the (Z)- and (E)-cyclodecene-1,4-dione compounds deriving from steroids, 2a,b and 3a,b, respectively, proceeds stereoselectively to give the corresponding ...
Electrochemical Deposition and Phase Structure of Electrodeposited Ni-W Alloys / Elektrohemijsko taloženje i fazna struktura legura Ni-W
(Serbian Chemical Society, 1999)
The induced deposition of W in the presence of iron-group metals has been known for a long time without a proper understanding of the mechanism of codeposition. Hints were made by several authors, concerning primarily a ...