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Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone
(Oxford : Pergamon-Elsevier Science Ltd, 2004)
Optically pure (-)-cytoxazone was synthesized, starting from methyl p-methoxycinnamate, in six steps and in 31%, overall yield. The required anti-aminoalcohol configuration was established by combining Sharpless asymmetric ...
Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with ethylene oxide
(Oxford : Pergamon-Elsevier Science Ltd, 2000)
Titanium tetrachloride promoted reaction of trimethylsilyl enol ethers with ethylene oxide affords homoaldol type products in moderate/good yields. The reaction is believed to proceed via the titanium enolates. (C) 2000 ...
The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
(Elsevier, 2003)
Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000® (BP) and Vulcan® XC-72 R (XC) were used as supporting materials. ...
Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5
(Wiley-Blackwell, 2007)
The kinetic parameters of the selective isothermal adsorption of ethanol from an
aqueous solution onto a hydrophobic zeolite type NaZSM-5 were determined
using a series of the so-called standard methods (the initial rate, ...
Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with epoxides
(Oxford : Pergamon-Elsevier Science Ltd, 2001)
Titanium tetrachloride promoted reaction of trimethylsilyl enol ethers with ethylene oxide affords homoaldol type products in moderate/good yields. Monosubstituted epoxides react regioselectively: the nucleophilic attack ...
The effect of electrochemically treated glassy carbon on the activity of supported Pt catalyst in methanol oxidation
(Elsevier, 2004)
Effect of electrochemical oxidation of glassy carbon on deposition of platinum particles and electrocatalytic activity of platinum supported on oxidized glassy carbon (Pt/GCOX) were studied for methanol oxidation in H2SO4 ...
Mixed steroidal 1,2,4,5-tetraoxanes: Antimalarial and antimycobacterial activity
(American Chemical Society (ACS), 2002)
Mixed 1,2,4,5-tetraoxanes possessing simple spirocycloalkane and spirocholic acid-derived substituents were prepared and shown to have significantly higher in vitro antimalarial activity than bis-substituted tetraoxanes. ...
Study on fisetin-aluminium(III) interaction in aqueous buffered solutions by spectroscopy and molecular modeling
(Elsevier Science Inc, New York, 2009)
Spectroscopic (UV/visible and IR) and theoretical studies were used to assess relevant interaction of fisetin, a tetrahydroxylated flavone molecule, and trivalent aluminium in a wide range of buffered aqueous solutions. ...
Adsorption-desorption noise in micromechanical resonant structures
(Elsevier, 2002)
In this paper we analyze adsorption-desorption (AD) noise in resonant microelectromechanical structures. This noise is generated by instantaneous differences in the rates of adsorption and desorption of contaminant molecules ...
Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C
(American Chemical Society (ACS), 2006)
The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The ...