Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C
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2006
Authors
Matović, Radomir
Ivkovic, Aleksandar
Manojlović, Marija
Tokic-Vujosevic, Zorana
Saičić, Radomir N.

Article (Published version)

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Show full item recordAbstract
The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.
Source:
Journal of Organic Chemistry, 2006, 71, 25, 9411-9419Publisher:
- Amer Chemical Soc, Washington
Projects:
DOI: 10.1021/jo061790j
ISSN: 0022-3263
PubMed: 17137368