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Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C

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2006
Authors
Matović, Radomir
Ivkovic, Aleksandar
Manojlović, Marija
Tokic-Vujosevic, Zorana
Saičić, Radomir N.
Article (Published version)
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Abstract
The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.
Source:
Journal of Organic Chemistry, 2006, 71, 25, 9411-9419
Publisher:
  • Amer Chemical Soc, Washington
Projects:
  • Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (RS-142021)

DOI: 10.1021/jo061790j

ISSN: 0022-3263

PubMed: 17137368

WoS: 000242426900019

Scopus: 2-s2.0-33845527881
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14
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2771
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