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Binding of metal ions and water molecules to nucleic acid bases: The influence of water molecule coordination to a metal ion on water–nucleic acid base hydrogen bonds
(International Union of Crystallography, 2019)
The interactions of nucleic acid bases with non-coordinated and coordinated water molecules were studied by analyzing data in the Protein Data Bank (PDB) and by quantum chemical calculations. The analysis of the data in ...
A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production
(Elsevier, 2020)
The present paper is focused on the development of a new environment-friendly methanolysis catalyst completely
based on waste materials: lignite coal fly ash and chicken eggshells. A novel catalyst based on CaO
supported ...
Novel non-enzymatic glucose sensing material based on pillared clay modified with cobalt
(Elsevier, 2019)
Cobalt oxide supported on pillared clay was synthesized and used as modifier of carbon paste electrode. Cyclic Voltammetry and Impedance Spectroscopy were employed to evaluate the performance of investigated electrode in ...
Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
(Springer Science and Business Media LLC, 2020)
The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the ...
Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
(Wiley, 2019)
α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until ...
Organocatalytic, Organic Oxidant Promoted, Enamine C−H Oxidation/Cyclopropanation Reaction
(Wiley, 2021)
Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions ...
Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects
(Elsevier, 2020)
A series of nine 5-(4-substituted phenylazo)-3-amido-6-hydroxy-4-methyl-2-pyridones were synthesized and characterized by FT–IR, 1H and 13C NMR, UV–Vis, and PL spectroscopy. Photophysical properties of the dyes were examined ...
Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation
(American Chemical Society (ACS), 2019)
Unsaturated oxyallyl cations with a suitably positioned alkene bond undergo 5-exo-cyclization with the formation of vinylcyclopentane derivatives. Alkyne analogues provide allenes. The reaction proceeds with a moderate to ...
Biochemical parameters in skin and muscle of Pelophylax kl. esculentus frogs: Influence of a cyanobacterial bloom in situ
(Elsevier, 2020)
There is little information in scientific literature as to how conditions created by a microcystin (MC) producing cyanobacterial bloom affect the oxidant/antioxidant, biotransformation and neurotoxicity parameters in adult ...
Antibacterial and Antibiofilm Activity of Flavonoid and Saponin Derivatives from Atriplex tatarica against Pseudomonas aeruginosa
(American Chemical Society (ACS), 2019)
A new flavonoid glucoside derivative, patuletin 3-O-(2-O-feruloyl)-β-D-glucuronopyranosyl-(1→2)-β-Dglucopyranoside, named atriplexin IV (1), and three new triterpenoid saponin derivatives, two sulfonylated, β-Dglucopyran ...