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Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation

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2019
Authors
Vulović, Bojan
Trmčić, Milena
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
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Abstract
Unsaturated oxyallyl cations with a suitably positioned alkene bond undergo 5-exo-cyclization with the formation of vinylcyclopentane derivatives. Alkyne analogues provide allenes. The reaction proceeds with a moderate to excellent level of stereoselectivity and allows for asymmetric induction in the reaction with chiral substrate.
Source:
Organic Letters, 2019, 21, 23, 9618-9621
Publisher:
  • ACS
Projects:
  • The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)
  • Serbian Academy of Sciences and Arts (Project No. F193)
  • Reinforcement of the Faculty of Chemistry, University of Belgrade, towards becoming a Center of Excellence in the region of WB for Molecular Biotechnology and Food research (EU-256716)

DOI: 10.1021/acs.orglett.9b03791

ISSN: 1523-7060

WoS: 000502163300071

Scopus: 2-s2.0-85076326919
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URI
http://cherry.chem.bg.ac.rs/handle/123456789/3819
http://cer.ihtm.bg.ac.rs/handle/123456789/3388
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