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Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
(Wiley-V C H Verlag Gmbh, Weinheim, 2015)
A series of heteropentanuclear oxalate-bridged Ru(NO)-Ln (4d-4f) metal complexes of the general formula (nBu(4)N)(5)[Ln{RuCl3(-ox)(NO)}(4)], where Ln=Y (2), Gd (3), Tb (4), Dy (5) and ox=oxalate anion, were obtained by ...
The role of spin states in the catalytic mechanism of the intra- and extradiol cleavage of catechols by O-2
(Royal Soc Chemistry, Cambridge, 2017)
Iron-dependent enzymes and biomimetic iron complexes can catalyze the ring cleavage of very inert, aromatic compounds. The mechanisms of these transformations and the factors that lead either to extradiol cleavage or ...
Evaluation of the effects of native minerals on the organic matter of Aleksinac oil shale based on the composition of free and bound bitumens
(Organic Geochemistry, 1992)
In order to evaluate the adsorption and catalytic effects of indigenous carbonates and silicates on the organic matter of Aleksinac oil shale, the free and the bound bitumens were isolated and analyzed by organic geochemical ...
Spin- and valley-polarized transport in a monolayer of MoS2
(Amer Physical Soc, College Pk, 2016)
We investigate dc and ac transport in a monolayer of MoS2 in the presence of an effective mass asymmetry, a momentum-dependent term, and an out-of plane or in-plane Zeeman term. Analytical results are presented for both ...
Remote electron plasmon polaron in graphene
(Amer Physical Soc, College Pk, 2012)
The Coulomb interaction and the correlation of a remote electron with a single layer of graphene is investigated in the presence of a magnetic field applied perpendicular to the graphene layer. The remote electron polarizes ...
Magnetic and electric control of spin- and valley-polarized transport across tunnel junctions on monolayer WSe2
(Amer Physical Soc, College Pk, 2017)
The recent experimental realization of high-quality WSe2 leads to the possibility of an efficient manipulation of its spin and valley degrees of freedom. Its electronic properties comprise a huge spin-orbit coupling, a ...
Integer quantum Hall effect in gapped single-layer graphene
(Amer Physical Soc, College Pk, 2012)
Analytical expressions for the Hall conductivity sigma(yx) and the longitudinal resistivity rho(xx) are derived in gapped, single-layer graphene using linear response theory. The gap 2 Delta, described by a mass term, is ...
Identification of p53 and Its Isoforms in Human Breast Carcinoma Cells
(Hindawi Publishing Corporation, New York, 2014)
In breast carcinoma, disruption of the p53 pathway is one of the most common genetic alterations. The observation that the p53 can express multiple protein isoforms adds a novel level of complexity to the outcome of p53 ...
Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen
(Royal Soc Chemistry, Cambridge, 2015)
Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in ...
Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes
(Wiley-V C H Verlag Gmbh, Weinheim, 2018)
The complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square ...