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Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

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2015
1794.pdf (394.3Kb)
Authors
Novkovic, L
Trmcic, M
Rodić, Marko V.
Bihelović, Filip
Zlatar, Matija
Matović, Radomir
Saičić, Radomir N.
Article (Published version)
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Abstract
Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.
Source:
RSC Advances, 2015, 5, 120, 99577-99584
Publisher:
  • Royal Soc Chemistry, Cambridge
Projects:
  • The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)
  • Reinforcement of the Faculty of Chemistry, University of Belgrade, towards becoming a Center of Excellence in the region of WB for Molecular Biotechnology and Food research (EU-256716)
  • humanitarian foundation "Hrast"
  • Serbian Academy of Sciences and Arts [F193]

DOI: 10.1039/c5ra13476e

ISSN: 2046-2069

WoS: 000365328000100

Scopus: 2-s2.0-84948440550
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/1796
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