CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrilic)
    • Serbian (Latin)
  • Login
View Item 
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes

Thumbnail
2018
2333.pdf (672.9Kb)
Authors
Wang, Lianke
Zlatar, Matija
Vlahović, Filip
Demeshko, Serhiy
Philouze, Christian
Molton, Florian
Gennari, Marcello
Meyer, Franc
Duboc, Carole
Gruden, Maja
Article (Published version)
Metadata
Show full item record
Abstract
The complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square pyramidal coordinated Fe-III ion. Unusually, all three complexes have intermediate spin ground states. Susceptibility measurements, powder cw X- and Q-band EPR spectra, and zero-field powder Mossbauer spectra show that all complexes display distinct magnetic anisotropy, which has been rationalized by DFT calculations.
Keywords:
density functional calculations / electronic structure / intermediate spin state / iron(III) / magnetic properties
Source:
Chemistry-A European Journal, 2018, 24, 20, 5091-5094
Publisher:
  • Wiley-V C H Verlag Gmbh, Weinheim
Projects:
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
  • COST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
  • China Scholarship Council
  • Deutsche Forschungsgemeinschaft (collaborative DFG/ANR project) [Me1313/14-1]
  • Serbian-French collaboration project [451-03-39/2016-09/06, 36224WB, ANR-11-LABX-003]

DOI: 10.1002/chem.201705989

ISSN: 0947-6539

PubMed: 29447424

WoS: 000429703700018

Scopus: 2-s2.0-85042682197
[ Google Scholar ]
9
6
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2335
Collections
  • Radovi istraživača / Researchers' publications
Institution
IHTM

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutionsAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB