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Computational study of the spin-state energies and UV-Vis spectra of bis(1,4,7-triazacyclononane) complexes of some first-row transition metal cations
(Royal Soc Chemistry, Cambridge, 2013)
We report here computed spin-state energies and UV-Vis spectra for several transition metal complexes with a triazacyclononane ligand. Our results show that the spin ground-state is correctly obtained with either OPBE or ...
Challenges in assignment of orbital populations in a high spin manganese(III) complex
(Royal Soc Chemistry, Cambridge, 2016)
Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation ...
Influence of peanut matrix on stability of allergens in gastric-simulated digesta: 2S albumins are main contributors to the IgE reactivity of short digestion-resistant peptides
(Wiley, Hoboken, 2018)
BackgroundMost food allergens sensitizing via the gastrointestinal tract are stable proteins that are resistant to pepsin digestion, in particular major peanut allergens, Ara h 2 and Ara h 6. Survival of their large fragments ...
Electrochemical behavior of palladium modified amino-functionalized macroporous copolymer
(Elsevier, 2017)
In this study, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) was synthesized by suspension copolymerization, functionalized by ring-opening reaction of the pendant epoxy groups with diethylene ...
Chemical modification of chloroperoxidase for enhanced stability and activity
(Elsevier Sci Ltd, Oxford, 2014)
Chloroperoxidase from Caldariomyces fumago (CPO, EC 1.11.1.10) is one of the most interesting enzymes from the group of heme peroxidases and has been extensively applied in synthetic processes. Nevertheless, the practical ...
Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid
(American Chemical Society (ACS), 2017)
For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in ...
Anti-quorum sensing activity, toxicity in zebrafish (Danio rerio) embryos and phytochemical characterization of Trapa natans leaf extracts
(Elsevier Ireland Ltd, Clare, 2018)
Ethnopharmacological relevance: Trapa natans L. (water chestnut or water caltrop) is a widespread aquatic plant, which has been cultivated for food and traditional medicine since ancient times. Pharmacological studies ...
Kiwifruit cysteine protease actinidin compromises the intestinal barrier by disrupting tight junctions
(Elsevier, 2016)
Background: The intestinal epithelium forms a barrier that food allergens must cross in order to induce sensitization. The aim of this study was to evaluate the impact of the plant-derived food cysteine protease - actinidin ...
Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites
(Elsevier, 2017)
A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized ...
Binary oxide ceramics for enhanced phenols degradation under simulated Solar light
(Wiley, Hoboken, 2018)
Solvothermal synthesis of ZrO2-TiO2 binary oxides and pure counterparts at 150 degrees C in water/isopropanol media is presented. Titanium (IV) isopropoxide and zirconium (IV) propoxide were used as precursors. XRD and TEM ...