CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrilic)
    • Serbian (Latin)
  • Login
View Item 
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Challenges in assignment of orbital populations in a high spin manganese(III) complex

Thumbnail
2016
Acc_C5DT03914B.pdf (1.206Mb)
Authors
Fitzpatrick, Anthony J.
Stepanović, Stepan
Mueller-Bunz, Helge
Gruden-Pavlović, Maja
Garcia-Fernandez, Pablo
Morgan, Grace G.
Article (Accepted Version)
Metadata
Show full item record
Abstract
Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.
Source:
Dalton Transactions, 2016, 45, 15, 6702-6708
Publisher:
  • Royal Soc Chemistry, Cambridge
Projects:
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
  • COST Action [CM1305]
  • Ramon y Cajal fellowship [RYC-2013-12515]
  • Cultural Service of the French Embassy in Ireland
  • Science Foundation Ireland [12/IP/1703]
  • Irish Higher Education Authority
  • National University of Ireland
  • University College Dublin
Note:
  • Published version: http://cer.ihtm.bg.ac.rs/handle/123456789/3624
  • This is peer-reviewed version of the following article: Fitzpatrick, A. J.; Stepanovic, S.; Müller-Bunz, H.; Gruden-Pavlović, M. A.; García-Fernández, P.; Morgan, G. G. Challenges in Assignment of Orbital Populations in a High Spin Manganese(Iii) Complex. Dalton Transactions 2016, 45 (15), 6702–6708. https://doi.org/10.1039/c5dt03914b

DOI: 10.1039/c5dt03914b

ISSN: 1477-9226

PubMed: 26974518

WoS: 000373994800044

Scopus: 2-s2.0-84964680292
[ Google Scholar ]
8
8
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/3625
Collections
  • Radovi istraživača / Researchers' publications
Institution
IHTM

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutionsAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB