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Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
New approach to the aromatization of ring B in 19-norsteroids and to the synthesis of equilenin-type compounds
(Royal Society of Chemistry, 1978)
When 7α-acetoxy-3,3 : 17,17-bis(ethylenedioxy)-5,10-epoxy-5β, 10β-oestran-6-one (2), formed by lead tetra-acetate acetoxylation of the parent compound (1), is heated with alkali, it undergoes ring B aromatization to give ...
The critical overpotential for zinc dendrite formation
(Kluwer Academic Publishers, 1979)
The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popov et al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there ...
Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 5-p-nitrobenzoates
(Pergamon Press, 1979)
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and ...
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
Transannular solvolysis reactions in seco-steroids containing a ten-membered ring.
(Pergamon Press, 1970)
Homoallylic interaction in steroidal cyclodecenyl systems
(Pergamon Press, 1974)
A new type of d.c. arc as spectrochemical light source
(Elsevier, 1974)
A new type of d.c. arc light source for spectrochemical purposes has been developed. The horizontal arc burning in a graphite tube is placed in an inhomogeneous magnetic field. The limits of detection of In and Pb have ...
Investigations of the Arc Burning in the Water Vapour Atmosphere
(Wiley, 1975)
The functions of thermal conductivity α(T) and electrical conductivity σ(T) for water vapour, within the temperature intervals 7700–8000 K and 2000–3500 K, were calculated. These calculations were performed by using the ...
Electric conductivity and viscosity of 1,4-benzenediol and hydroxybenzene solutions in concentrated sulphuric acid
(Elsevier, 1974)
Many authors have dealt with the formation of the complexes of 1,4-benzenediol and some metals in concentrated sulphuric acid. However, no data can be found in the literature either on the reaction of 1,4-benzenediol with ...