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Acceleration of electrocatalytic reactions by pulsation of potential: Oxidation of formic acid on Pt and Pt/Pbads electrodes
(Pergamon Press, 1978)
Pulsating potential electrolysis has been applied to one typical electrocatalytic reaction ie, the oxidation of formic acid on platinum and platinum partially covered by lead adatoms electrodes. It has been found that much ...
An apparatus for simultaneous determination of electrical conductivity and thermogravimetric curves of solid systems
(Springer, 1975)
A new apparatus for measurement of electrical conductivity during thermogravimetric analysis is described. Results of an investigation of the water-zeolite system in the interval -200° up to +450° prove the suitability of ...
Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
(Elsevier, 1977)
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange ...
Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions
(Pergamon Press, 1978)
The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Studies of the deposition of cadmium on foreign substrates
(Elsevier, 1977)
Cadmium deposition on nickel, lead, silver, gold and copper has been studied by the potential sweep and potentiostatic method with a simultaneous observation of the surface by optical microscopy. It was found that the ...
Individual ionic activities and mass transfer in anodic chlorate formation
(Switzerland : Springer Nature, 1973)
The individual activity of hypochlorite ion in concentrated neutral salt (NaCl-NaClO3) solutions has been estimated kinetically by measurement of the Faradaic efficiency in a chlorate producing system comprised of a cell ...
Rotating two-ring electrodes as a tool for electrochemical investigations of gas-evolving reactions
(Elsevier, 1972)
It is shown that two concentric ring electrodes located on a rotating disc surface can be used as an instrument for chemical and electrochemical analysis of gas-evolving reactions up to rates of gas evolution from the inner ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...