Претраживање
Приказ резултата 31-40 од 124
Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
(Wiley, 2019)
α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until ...
Organocatalytic, Organic Oxidant Promoted, Enamine C−H Oxidation/Cyclopropanation Reaction
(Wiley, 2021)
Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions ...
Study of stacking interactions between two neutral tetrathiafulvalene molecules in Cambridge Structural Database crystal structures and by quantum chemical calculations
(Wiley, 2019)
Tetrathiafulvalene (TTF) and its derivatives are very well known as electron donors with widespread use in the field of organic conductors and superconductors. Stacking interactions between two neutral TTF fragments were ...
Toxicity investigation of CeO2 nanoparticles coated with glucose and exopolysaccharides levan and pullulan on the bacterium Vibrio fischeri and aquatic organisms Daphnia magna and Danio rerio
(Elsevier, 2021)
Cerium oxide nanoparticles (nCeO2) have widespread applications, but they can be hazardous to the environment. Some reports indicate the toxic effect of nCeO2 on tested animals, but literature data are mainly contradictory. ...
Toxicity investigation of CeO2 nanoparticles coated with glucose and exopolysaccharides levan and pullulan on the bacterium Vibrio fischeri and aquatic organisms Daphnia magna and Danio rerio
(Elsevier, 2021)
Cerium oxide nanoparticles (nCeO2) have widespread applications, but they can be hazardous to the environment. Some reports indicate the toxic effect of nCeO2 on tested animals, but literature data are mainly contradictory. ...
Degradation of α-nitroso-β-naphthol by UVA-B activated peroxide, persulfate and monopersulfate oxidants in water
(Elsevier, 2019)
Flotation reagents, especially new chelating agents represented by α-nitroso-β-naphthol, are the main components of cobalt mining drainage. This study reports the degradation of α-nitroso-β-naphthol by simulated UVA-B ...
Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
(Springer Science and Business Media LLC, 2020)
The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the ...
Carbohydrate – Protein aromatic ring interactions beyond CH/π interactions: A Protein Data Bank survey and quantum chemical calculations
(Elsevier, 2020)
The geometries of the contacts between monosaccharides and aromatic rings of amino acids found in X-ray crystallography structures, in the Protein Data Bank (PDB), were analyzed, while the energies of the interactions were ...
Activation of Oxone® with plasma deposited mixed cobalt and alumina oxide for the dye degradation
(Elsevier, 2020)
The aim of this work is to examine the possibility of the formation of cobalt doped Al2O3 coatings on aluminum substrate by plasma electrolytic oxidation process (PEO) and application of the obtained material as catalyst ...
Characterisation of the binding of dihydro-alpha-lipoic acid to fibrinogen and the effects on fibrinogen oxidation and fibrin formation
(Elsevier, 2020)
A reduced form of the alpha-lipoic acid, dihydro-alpha-lipoic acid (DHLA) is a potent, naturally occurring antioxidant which can be consumed as food constituent or as supplement at doses up to 600 mg/day. DHLA has inhibitory ...