Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
Authorized Users Only
Article (Published version)
Royal Society of Chemistry
MetadataShow full item record
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Source:Journal of the Chemical Society, Chemical Communications, 1979, 18, 817-818
- Royal Society of Chemistry