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Effect of the support and the reduction temperature on the formation of metallic nickel phase in Ni/silica gel precursors of vegetable oil hydrogenation catalysts
(Maik Nauka/Interperiodica/Springer, New York, 2011)
Ni/SiO(2) materials with identical composition (SiO(2)/Ni = 1.0) have been synthesized by precipitation of Ni(NO(3))(2) center dot 6H(2)O solution with Na(2)CO(3) solution on the silica gel, obtained at three different pH ...
Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction
(Maik Nauka/Interperiodica/Springer, New York, 2009)
The kinetic investigations of the malonic acid decomposition (8.00 x 10(-3) mol dm(-3) a parts per thousand currency sign [CH(2)(COOH)(2)](0) a parts per thousand currency sign 4.30 x 10(-2) mol dm(-3)) in the Belousov-Zhabotinsky ...
Monolayer gas adsorption in plasmonic sensors: Comparative analysis of kinetic models
(Maik Nauka/Interperiodica/Springer, New York, 2013)
The analysis of adsorption kinetics is given, assuming no dissociative adsorption takes place and no multiple binding sites exist. The phenomenological nonlinear model and the simple linear model are considered from the ...
Mixed-mode oscillations and chaos in return maps of an oscillatory chemical reaction
(Maik Nauka/Interperiodica/Springer, New York, 2015)
The return maps, as an element of mathematical phenomenology appropriate for general examinations of complex dynamic states of the oscillatory systems were used to detect and explain the evolution of mixed-mode oscillations ...
Intermittent Chaos in the Bray-Liebhafsky Oscillator. Dependence of Dynamic States on the Iodate Concentration
(Maik Nauka/Interperiodica/Springer, New York, 2017)
Chaotic dynamic states with intermittent oscillations were generated in a Bray-Liebhafsky (BL) oscillatory reaction in an isothermal open reactor i.e., in the continuously-fed well-stirred tank reactor (CSTR) when the ...
Methanol electrooxidation in alkaline solutions on platinum-based electrodes: Classical and dynamical approach
(Maik Nauka/Interperiodica/Springer, New York, 2013)
The electrochemical oxidation of methanol has been carefully studied due to its application in fuel cells. In this work electrooxidation of methanol was investigated on bare platinum electrode, the platinum electrode covered ...
Numerical evidence of complex nonlinear phenomena of the Belousov-Zhabotinsky oscillatory reaction under batch conditions
(Maik Nauka/Interperiodica/Springer, New York, 2013)
By numerical calculations based on our previously proposed model with Br2O intermediate species we were able to simulate complex evolution of the Belousov-Zhabotinsky (BZ) reaction under batch conditions. In the defined ...
Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor
(Maik Nauka/Interperiodica/Springer, New York, 2007)
Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was ...
Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator
(Maik Nauka/Interperiodica/Springer, New York, 2009)
The infuence of poly-4-vinylpyridine-co-divinylbenzene-Co2+ catalyst on the Bray-Liebhafsky (BL) oscillator used as the matrix for establishing catalyst's activity was analyzed. The addition of the catalyst do not change ...
Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction
(Maik Nauka/Interperiodica/Springer, New York, 2009)
We applied multifractal analysis on time series obtained by deterministic simulation of the Bray-Liebhafsky oscillatory reaction. Large deviation spectrum was used to represent multifractal properties of the attractor. We ...