Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was characterized by means of SEM-EDX, FTIR, diffuse reflectance UV-Vis, N-2 sorption, and mercury porosimetry. Activation energies were determined under steady state conditions for the net production of cyclohexanone and cyclohexanol and for cyclohexane and oxygen net consumption. Some activation energies were lower than the ones reported for the uncatalyzed process, indicating that the catalyst played an important role in the initiation of the free-radical reaction.
Source:
Russian Journal of Physical Chemistry A, 2007, 81, 9, 1398-1401
TY - JOUR
AU - Lončarević, Davor
AU - Krstić, Jugoslav
AU - Banković, Predrag
AU - Anić, Slobodan
AU - Čupić, Željko
PY - 2007
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/295
AB - Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was characterized by means of SEM-EDX, FTIR, diffuse reflectance UV-Vis, N-2 sorption, and mercury porosimetry. Activation energies were determined under steady state conditions for the net production of cyclohexanone and cyclohexanol and for cyclohexane and oxygen net consumption. Some activation energies were lower than the ones reported for the uncatalyzed process, indicating that the catalyst played an important role in the initiation of the free-radical reaction.
PB - Maik Nauka/Interperiodica/Springer, New York
T2 - Russian Journal of Physical Chemistry A
T1 - Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor
VL - 81
IS - 9
SP - 1398
EP - 1401
DO - 10.1134/S0036024407090099
ER -
@article{
author = "Lončarević, Davor and Krstić, Jugoslav and Banković, Predrag and Anić, Slobodan and Čupić, Željko",
year = "2007",
abstract = "Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was characterized by means of SEM-EDX, FTIR, diffuse reflectance UV-Vis, N-2 sorption, and mercury porosimetry. Activation energies were determined under steady state conditions for the net production of cyclohexanone and cyclohexanol and for cyclohexane and oxygen net consumption. Some activation energies were lower than the ones reported for the uncatalyzed process, indicating that the catalyst played an important role in the initiation of the free-radical reaction.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor",
volume = "81",
number = "9",
pages = "1398-1401",
doi = "10.1134/S0036024407090099"
}
Lončarević, D., Krstić, J., Banković, P., Anić, S.,& Čupić, Ž.. (2007). Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 81(9), 1398-1401.
https://doi.org/10.1134/S0036024407090099
Lončarević D, Krstić J, Banković P, Anić S, Čupić Ž. Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor. in Russian Journal of Physical Chemistry A. 2007;81(9):1398-1401.
doi:10.1134/S0036024407090099 .
Lončarević, Davor, Krstić, Jugoslav, Banković, Predrag, Anić, Slobodan, Čupić, Željko, "Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor" in Russian Journal of Physical Chemistry A, 81, no. 9 (2007):1398-1401,
https://doi.org/10.1134/S0036024407090099 . .
