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Substituent efects on the carbon-13 chemical shifts in α-phenylpyridylacrylic acids
(Elsevier Science Publishers B.V., 1992)
The 13C N.M.R. spectra of some substituted α-phenylpyridylacrylic acids, α-phenyl, α-(3-pyrydyl) and α-(3-pyrydyl-N-oxide) cinnamic acids were determined in deuterated dimethyl sulfoxide (d6-DMSO). It has been shown that ...
The initiation of dendritic growth of electrodeposited copper on a rotating disc electrode with changing copper concentration and diffusion layer thickness
(Elsevier, 1992)
It is shown that the critical overpotential of dendritic growth initiation increases with increasing copper concentration under identical hydrodynamic conditions, as well as with increasing rotation speed to the rde (rotating ...
Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
(Elsevier, 1992)
The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid ...
Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides
(Elsevier Science Publishers B.V, 1992)
As a part of a study on the structural characteristics of some new various N-alkyl-N-substituted 2-phenylacetamides the infrared and 1 H N.M.R. spectra were obtained and interpreted. The synthesis of a various N-n-propyl-N-alkyl ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Coated-wire and composite ion-selective electrodes based on doped poly(pyrrole)
(Royal Society of Chemistry, 1992)
Chemically and electrochemically prepared doped poly(pyrrole) has been evaluated as a membrane component for ion-selective electrodes (ISEs). Two types of ISE were prepared: coated-wire electrodes (CWEs) and classical ISEs ...
Oxygen reduction on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in alkaline solution. A rotating disc-ring study
(Elsevier, 1992)
The kinetics of oxygen reduction have been studied on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in 0.1 M NaOH by a rotating disc-ring method. A very high activity of these surfaces for O2 reduction was demonstrated. ...
Degradative side reactions in the syntheses of exactly alternating silarylene-siloxane polymers
(Springer, 1992)
Four principal synthetic methods for preparation of exactly alternating silarylene-siloxane polymers: the chlorosilane, the acetoxysilane, the aminosilane and the ureidosilane polymerization reactions, were compared under ...
Opening of the Macrocyclic Ring in 5,10:8,9‐Disecosteroids ( = Steroklastanes)
(Weinheim : Wiley-VCH Verlag GmbH & Co., 1992)
Catalytic hydrogenation of the Δ3‐unsaturated (9R,10 R)‐ and (9S,10 S)‐epoxyenol lactones 3a, b., and 4a, b., respectively, affords, in addition to the expected saturated epoxylactones 5a, b and 7a, b, also open‐chain ...
Phase-structure analysis of brass by anodic linear-sweep voltammetry
(Springer, 1992)
Anodic linear-sweep voltammetry (ALSV) was applied to electrodeposited alloy layers and to metallurgically obtained Cu−Zn alloys of different composition and structure. Metallurgically obtained samples covered the range ...