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Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...
The effect of faradaic processes on the resonance of electrochemical cells
(Elsevier, 1976)
Electrolytic cells consisting of mercury electrodes immersed into pure aqueous sulphuric acid solution (ideally polarizable electrodes) and in the one containing Ti3+/Ti4+ redox couple (presence of a faradaic process) were ...
Electrochemical oxidation of formic acid at noble metals: Catalytic effects of foreign metal monolayers
(Elsevier, 1977)
The catalytic effects of a submonolayer of lead on noble metals have been shown and discussed in terms of a previously published model. A theoretical analysis of these effects is presented. It was demonstrated that foreign ...
Molybdenum and hydroxybenzene complexes in concentrated sulphuric acid
(Elsevier, 1976)
It is already known [1--5] that Ti, W, V, Mo and some other metals form
coloured complexes with 1,4-benzenediol in concentrated sulphuric acid. We
have also found that hydroxybenzene has similar properties. Papers found ...
Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
Investigation of the anodic processes on platinum in perchlorate and chlorate solutions by linear sweep voltammetry using the rotating double-ring electrodes
(Elsevier, 1976)
There have been several attempts to elucidate events occurring on platinum immersed into pure perchloric acid solutions, when submitted to high anodic polarisation. The polarisation curve was shown to exhibit two levels, ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...
Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
Catalytic effects of monolayers of metals deposited at underpotentials: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was recently shown that the monolayers of some metals deposited at underpotentials
on gold can substantially increase the rates of some redox reactions 1 , and the
rate of oxygen reduction:. This note reports the ...