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Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
(Elsevier, 1987)
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the ...
Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives
(Elsevier, 1985)
Thermal decomposition of steroidal 5α,8α-peroxides (such as 1) resulted in bisfragmentation of the C(5)-C(10) and C(8)-C(9) bonds, and elimination of acetic acid, to produce a new type of bicyclic compounds, namely ...
Local film thickness and photoresponse of thin anodic TiO2 films on polycrystalline titanium
(Elsevier, 1989)
Auger depth profiling was used to determine the local film thickness of a thin anodic oxide grown on a polycrystalline Ti substrate. The oxide thickness was studied as a function of substrate crystallography and final ...
Electrosorption of hydrogen and sulphuric acid anions on single-crystal platinum stepped surfaces. Part I. The [110] zone
(Elsevier, 1988)
The adsorption of hydrogen and sulphuric acid anions has been studied on single-crystal platinum stepped surfaces from the [110] zone. Both processes depend on the orientation of the electrode surface. The multiple states ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part II. Applications
(Elsevier, 1987)
The criteria obtained for a new reaction scheme of O2 reduction have been applied to experimental data from several laboratories. The possibilities and merits of a new scheme have been analysed. Some results, not fully ...
Lanthanum-molybdenum coating for hydrogen evolution on titanium
(Switzerland : Springer Nature, 1984)
There is practical interest in the use of titanium as a cathode material in brine electrolysis processes. The overvoltage of hydrogen evolution on titanium is, however, very high and, at the same time, hydrogen penetrates ...
Treatment of electrostatic effects within the molecular mechanics Method. 2
(American Chemical Society, 1983)
The previously developed general method, which includes induction by dipoles in polarizable bonds and the solvation of molecular dipoles and quadrupoles, was used to calculate molecular dipole moments and to predict ...
Mass-spectrometric analysis of the products formed in a D.C. Arc Plasma / Massenspektrometrische Analyse der im Gleichstrombogen-Plasma gebildeten Produkte
(Springer Nature, 1980)
The carbon content was determined in the plasma of horizontal electric arc discharging between carbon electrodes in a) a graphite tube and b) a ceramic tube, in the presence of an inhomogeneous magnetic field. After 20 s ...
Free-radical oxidative transformations of androst-4-ene-3β,9α,17β-triol 3,17-diacetate
(Tetrahedron, 1988)
The oxidation of androst-4-ene-3β,9α,17β-triol 3,17-diacetate (2) with lead tetraacetate resulted mainly In β-fragmentation of the C(9)-C(10) bond to give a mixture of 10α- and 10β-acetoxy-Δ4-unsaturated 9,10-seco-steroidal ...
The solvent effect on the conformational equilibrium of 1,3-dichloro-5-methylcylclohexane
(Elsevier, 1985)
The conformational equilibrium has been measured for r-1,c-3-dichloro-t-5-methylcyclohexane(2) in six solvents from the 500 MHz and 400 MHz 1H NMR spectra. The room-temperature and low-temperature C1H couplings are used ...