Thermal decomposition of steroidal 5α,8α-peroxides (such as 1) resulted in bisfragmentation of the C(5)-C(10) and C(8)-C(9) bonds, and elimination of acetic acid, to produce a new type of bicyclic compounds, namely 5,10;8,9-diseco-steroid derivatives (such as 2). some chemical transformations of product 2 are described.
Keywords:
5,10:8,9 disecosteroid / drug analysis / drug identification / drug synthesis / mass spectrometry / nonhuman / nuclear magnetic resonance / preliminary communication / priority journal / theoretical study
TY - JOUR
AU - Lorenc, Ljubinka B.
AU - Bondarenko, Lidija
AU - Mihailović, Milhailo Lj.
PY - 1985
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4514
AB - Thermal decomposition of steroidal 5α,8α-peroxides (such as 1) resulted in bisfragmentation of the C(5)-C(10) and C(8)-C(9) bonds, and elimination of acetic acid, to produce a new type of bicyclic compounds, namely 5,10;8,9-diseco-steroid derivatives (such as 2). some chemical transformations of product 2 are described.
PB - Elsevier
T2 - Tetrahedron Letters
T1 - Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives
VL - 26
IS - 3
SP - 389
EP - 392
DO - 10.1016/S0040-4039(01)80825-X
ER -
@article{
author = "Lorenc, Ljubinka B. and Bondarenko, Lidija and Mihailović, Milhailo Lj.",
year = "1985",
abstract = "Thermal decomposition of steroidal 5α,8α-peroxides (such as 1) resulted in bisfragmentation of the C(5)-C(10) and C(8)-C(9) bonds, and elimination of acetic acid, to produce a new type of bicyclic compounds, namely 5,10;8,9-diseco-steroid derivatives (such as 2). some chemical transformations of product 2 are described.",
publisher = "Elsevier",
journal = "Tetrahedron Letters",
title = "Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives",
volume = "26",
number = "3",
pages = "389-392",
doi = "10.1016/S0040-4039(01)80825-X"
}
Lorenc, L. B., Bondarenko, L.,& Mihailović, M. Lj.. (1985). Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives. in Tetrahedron Letters
Elsevier., 26(3), 389-392.
https://doi.org/10.1016/S0040-4039(01)80825-X
Lorenc LB, Bondarenko L, Mihailović ML. Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives. in Tetrahedron Letters. 1985;26(3):389-392.
doi:10.1016/S0040-4039(01)80825-X .
Lorenc, Ljubinka B., Bondarenko, Lidija, Mihailović, Milhailo Lj., "Transformation of steroidal 5α,8α-peroxides to the 14-membered ring containing 5,10;8,9-diseco-steroid derivatives" in Tetrahedron Letters, 26, no. 3 (1985):389-392,
https://doi.org/10.1016/S0040-4039(01)80825-X . .
