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Hydrogen adsorption on single-crystal platinum electrodes in alkaline solutions
(Elsevier, 1992)
Hydrogen adsorption on single-crystal platinum low-index and stepped surfaces was studied in 0.1 M and 0.01 M NaOH solutions. A strong dependence on the crystallographic orientation of the electrode surface was found. The ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
(Elsevier, 1992)
The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid ...
Oxygen reduction on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in alkaline solution. A rotating disc-ring study
(Elsevier, 1992)
The kinetics of oxygen reduction have been studied on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in 0.1 M NaOH by a rotating disc-ring method. A very high activity of these surfaces for O2 reduction was demonstrated. ...
Electrochemical indication of surface reconstruction of (NO), (311) and (111) gold faces in alkaline solutions
(Elsevier, 1993)
The specific adsorption of OH- anion and the changes in the surface atomic structures of (100), (311) and (111) gold faces with charge density are discussed on the basis of cyclic voltammograms and differential capacity-potential ...
Kinetic and mechanistic study of methanol oxidation on a Pt(111) surface in alkaline media
(Elsevier, 1996)
A comparative study of methanol oxidation on a Pt(111) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. The surface activity was directly correlated to the OHad species ...
Anodic oxidation of small organic molecules on silver modified glassy carbon electrodes
(Elsevier, 1991)
Small organic molecules (HCOOH, C,H,(OH),, CH,OH, CH,O, etc.) have become more interesting with the possibility of their application in fuel cells. Therefore, the anodic oxidation of such molecules has been studied on a ...
Structural effects in electrocatalysis. Ethylene glycol oxidation on platinum single-crystal surfaces
(Elsevier, 1991)
The oxidation of ethylene glycol (EG) has been studied on platinum single-crystal surfaces in 0.1 M NaOH. A strong structural dependence of the reaction kinetics was found for all 12 single-crystal orientations investigated. ...
Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
(Elsevier, 1997)
Electrochemical reduction of carbon dioxide is still of great interest in the fields of theoretical and applied electrochemistry. Ruthenium is one of the metals with an intermediate hydrogen evolution overpotential which ...