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ALSV investigation of the phase composition of electrolytic Cu + Sn alloys

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1991
Authors
Skibina, Lj M.
Stevanović, Jasmina S.
Despić, Aleksandar R.
Article (Published version)
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Abstract
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.
Keywords:
phase composition / Cu + Sn alloys / graphite / voltammograms / electrochemistry / alloy
Source:
Journal of Electroanalytical Chemistry, 1991, 310, 1-2, 391-401
Publisher:
  • Elsevier
Projects:
  • The Research Fund of Serbia

DOI: 10.1016/0022-0728(91)85274-S

ISSN: 1572-6657

Scopus: 2-s2.0-0001407176
[ Google Scholar ]
29
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4389
Collections
  • Radovi istraživača / Researchers' publications
Institution
IHTM
TY  - JOUR
AU  - Skibina, Lj M.
AU  - Stevanović, Jasmina S.
AU  - Despić, Aleksandar R.
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4389
AB  - Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
VL  - 310
IS  - 1-2
SP  - 391
EP  - 401
DO  - 10.1016/0022-0728(91)85274-S
ER  - 
@article{
author = "Skibina, Lj M. and Stevanović, Jasmina S. and Despić, Aleksandar R.",
year = "1991",
url = "https://cer.ihtm.bg.ac.rs/handle/123456789/4389",
abstract = "Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys",
volume = "310",
number = "1-2",
pages = "391-401",
doi = "10.1016/0022-0728(91)85274-S"
}
Skibina LM, Stevanović JS, Despić AR. ALSV investigation of the phase composition of electrolytic Cu + Sn alloys. Journal of Electroanalytical Chemistry. 1991;310(1-2):391-401
Skibina, L. M., Stevanović, J. S.,& Despić, A. R. (1991). ALSV investigation of the phase composition of electrolytic Cu + Sn alloys.
Journal of Electroanalytical ChemistryElsevier., 310(1-2), 391-401.
https://doi.org/10.1016/0022-0728(91)85274-S
Skibina Lj M., Stevanović Jasmina S., Despić Aleksandar R., "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys" 310, no. 1-2 (1991):391-401,
https://doi.org/10.1016/0022-0728(91)85274-S .

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