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The electrocatalytic properties of the oxides of noble metals in the electro-oxidation of some organic molecules
(Elsevier, 1997)
The electro-oxidation of organic compounds on gold and silver electrodes can occur either in a potential range more negative than that where the metal oxides are formed or within the more positive range where the surface ...
Kinetic and mechanistic study of methanol oxidation on a Pt 100/ surface in alkaline media
(Elsevier, 1998)
A comparative study of methanol oxidation on a Pt(100) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. It was shown that Pt(100) adsorbs OH and 'poisoning species'. ...
The influence of OH- chemisorption on the catalytic properties of gold single crystal surfaces for oxygen reduction in alkaline solutions
(Elsevier, 1996)
Oxygen reduction on gold single crystal electrodes of various orientations, Au(hkl), in 0.1 M NaOH was studied by rotating disk electrode and rotating disk ring electrode techniques, with a goal to correlate the physical ...
A New Approach to Metal Electrodeposition at a Periodically Change Rate. Part I. The Reversing Overpotential Method
(Elsevier, 1999)
A method of increasing the apparent deposition exchange current density value in reversing overpotential (RO) copper electrodeposition is described. In pulsating overpotential (PO) metal electrodeposition, the current ...
Structural effects in electrocatalysis. Oxidation of D-glucose on single crystal platinum electrodes in alkaline solution
(Elsevier, 1991)
Electrochemical oxidation of D-glucose has been studied in 0.1 M NaOH on single crystal platinum electrodes with thirteen different orientations. The reaction rate depends strongly on the crystallographic orientation of ...
Hydrogen adsorption on single-crystal platinum electrodes in alkaline solutions
(Elsevier, 1992)
Hydrogen adsorption on single-crystal platinum low-index and stepped surfaces was studied in 0.1 M and 0.01 M NaOH solutions. A strong dependence on the crystallographic orientation of the electrode surface was found. The ...
Oscillatory phenomena in oxygen and hydrogen peroxide reduction on the Au(100) electrode surface in alkaline solutions
(Elsevier, 1992)
In this work we report preliminary data for oscillatory behavior found in oxygen and hydrogen peroxide reduction on a rotating gold electrode with (100) orientation in alkaline solutions.
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
(Elsevier, 1992)
The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid ...