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Organocatalytic, Organic Oxidant Promoted, Enamine C−H Oxidation/Cyclopropanation Reaction
(Wiley, 2021)
Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions ...
Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation
(American Chemical Society (ACS), 2019)
Unsaturated oxyallyl cations with a suitably positioned alkene bond undergo 5-exo-cyclization with the formation of vinylcyclopentane derivatives. Alkyne analogues provide allenes. The reaction proceeds with a moderate to ...
The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy
(Elsevier, 2019)
In this work an attempt was made to produce epoxy coating doped with ceria (CeO2) and/or zirconia (ZrO2) nanoparticles, in single step electrophoretric deposition process. Deposition was carried out on AA6060 cataforetically ...
Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation
(Elsevier, 2019)
Aluminum pillared clay was synthesized and impregnated with Co2+ (CoAP), using incipient wetness impregnation method. The obtained CoAP was characterized by chemical analysis, XRPD, SEM with EDS, XPS and low temperature ...
Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
(Springer Science and Business Media LLC, 2020)
The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the ...
Toxicity investigation of CeO2 nanoparticles coated with glucose and exopolysaccharides levan and pullulan on the bacterium Vibrio fischeri and aquatic organisms Daphnia magna and Danio rerio
(Elsevier, 2021)
Cerium oxide nanoparticles (nCeO2) have widespread applications, but they can be hazardous to the environment. Some reports indicate the toxic effect of nCeO2 on tested animals, but literature data are mainly contradictory. ...
Novel non-enzymatic glucose sensing material based on pillared clay modified with cobalt
(Elsevier, 2019)
Cobalt oxide supported on pillared clay was synthesized and used as modifier of carbon paste electrode. Cyclic Voltammetry and Impedance Spectroscopy were employed to evaluate the performance of investigated electrode in ...
Carbohydrate – Protein aromatic ring interactions beyond CH/π interactions: A Protein Data Bank survey and quantum chemical calculations
(Elsevier, 2020)
The geometries of the contacts between monosaccharides and aromatic rings of amino acids found in X-ray crystallography structures, in the Protein Data Bank (PDB), were analyzed, while the energies of the interactions were ...
Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum
(Elsevier, 2020)
Chemical vapour deposition (CVD) is a promising method for producing large-scale graphene (Gr). Nevertheless, microscopic inhomogeneity of Gr grown on traditional metal substrates such as copper or nickel results in a ...
Characterisation of the binding of dihydro-alpha-lipoic acid to fibrinogen and the effects on fibrinogen oxidation and fibrin formation
(Elsevier, 2020)
A reduced form of the alpha-lipoic acid, dihydro-alpha-lipoic acid (DHLA) is a potent, naturally occurring antioxidant which can be consumed as food constituent or as supplement at doses up to 600 mg/day. DHLA has inhibitory ...