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Identification of intermetallic compounds in electrodeposited copper-cadmium alloys by electrochemical techniques
(Elsevier, 1989)
Anodic sweep voltammetry was used to identify different intermetallic compounds and assess their amount in copper-cadmium alloys. Four compounds are found in thin (1–8 μm) electroplated alloy films: CuCd3, Cu5Cd8, Cu4Cd3 ...
Oxygen reduction on a ruthenium electrode in acid electrolytes
(Elsevier, 1986)
The kinetics and mechanism of O2 reduction on an Ru electrode in acid electrolytes have been measured by using a disc—ring method. The reaction proceeds through a “parallel” mechanism with the exchange of approximately ...
The effect of anions on the electrochemical behaviour of aluminium
(Elsevier, 1983)
Aluminum has been known to exhibit widely different electrochemical properties in different aqueous electrolytes. Thus, OH- ions in strongly alkaline solutions reveal its strong affinity to water by dissolving its protective ...
Abnormal polarization change in anodic dissolution of aluminium at high current densities
(Elsevier, 1981)
Two types of anodic oxidation of aluminum have been recognized in the past: a) oxidation requiring a steady increase of voltage drop across the interface up to a few hundred volts in order to overcome the resistance of ...
Optical and electrochemical study of underpotential deposition of bismuth on gold electrode
(Elsevier, 1980)
The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with ...
Structural effects in electrocatalysis: oxidation of formaldehyde on gold and platinum single crystal electrodes in alkaline solution
(Elsevier, 1984)
The oxidation of formaldehyde in sodium hydroxide solution has been studied on platinum and gold single crystal electrodes with the (111), (110) and (100) orientations. There is apparently no structural sensitivity of this ...
Deposition of zinc of foreign substrates
(Elsevier, 1982)
Initial stage of deposition of zinc from buffered zinc sulphate solution (pH = 3.55) was studied using platinum, gold and graphite as substrates. The phenomenon of underpotential deposition, noted by recording potential ...
Local film thickness and photoresponse of thin anodic TiO2 films on polycrystalline titanium
(Elsevier, 1989)
Auger depth profiling was used to determine the local film thickness of a thin anodic oxide grown on a polycrystalline Ti substrate. The oxide thickness was studied as a function of substrate crystallography and final ...
Activation of aluminium in chloride containing solutions
(Elsevier, 1988)
Galvanostatic transients were recorded for anodic dissolution of high purity aluminium in neutral chloride solutions. All transients, except at very low current densities (below 50 μA cm-2), are characterized by an overshoot ...
Optical and electrochemical study of cation adsorption on oxide layers on gold and platinum electrodes
(Elsevier, 1985)
It has been shown that the adsorption of Bi3+ and Tl+ cations occurs on oxide layers of Au and Pt electrodes in acid solutions. The initial stages of oxide formation and reduction are inhibited. The effect increases with ...