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Optical and electrochemical study of underpotential deposition of bismuth on gold electrode

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1980
Authors
Adžić, Radoslav R.
Jovančićević, V.
Podlavicki, M.M.
Article (Published version)
Metadata
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Abstract
The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with the calculated spectrum. A satisfactory agreement between experimental and calculated spectra was found. ΔR/R values have been used to determine the surface concentration of Biad which then has been used to calculate the electrosorption valence of Biad. It has been found that γBi = 2.6. The optical evidence of interaction of Bi ions with gold oxide has been obtained.
Keywords:
electrochemistry / electrode / electrochemical / bismuth
Source:
Electrochimica Acta, 1980, 25, 9, 1143-1146
Publisher:
  • Elsevier

DOI: 10.1016/0013-4686(80)87111-8

ISSN: 0013-4686

Scopus: 2-s2.0-0019058718
[ Google Scholar ]
19
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4413
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Adžić, Radoslav R.
AU  - Jovančićević, V.
AU  - Podlavicki, M.M.
PY  - 1980
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4413
AB  - The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with the calculated spectrum. A satisfactory agreement between experimental and calculated spectra was found. ΔR/R values have been used to determine the surface concentration of Biad which then has been used to calculate the electrosorption valence of Biad. It has been found that γBi = 2.6. The optical evidence of interaction of Bi ions with gold oxide has been obtained.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Optical and electrochemical study of underpotential deposition of bismuth on gold electrode
VL  - 25
IS  - 9
SP  - 1143
EP  - 1146
DO  - 10.1016/0013-4686(80)87111-8
ER  - 
@article{
author = "Adžić, Radoslav R. and Jovančićević, V. and Podlavicki, M.M.",
year = "1980",
abstract = "The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with the calculated spectrum. A satisfactory agreement between experimental and calculated spectra was found. ΔR/R values have been used to determine the surface concentration of Biad which then has been used to calculate the electrosorption valence of Biad. It has been found that γBi = 2.6. The optical evidence of interaction of Bi ions with gold oxide has been obtained.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Optical and electrochemical study of underpotential deposition of bismuth on gold electrode",
volume = "25",
number = "9",
pages = "1143-1146",
doi = "10.1016/0013-4686(80)87111-8"
}
Adžić, R. R., Jovančićević, V.,& Podlavicki, M.M.. (1980). Optical and electrochemical study of underpotential deposition of bismuth on gold electrode. in Electrochimica Acta
Elsevier., 25(9), 1143-1146.
https://doi.org/10.1016/0013-4686(80)87111-8
Adžić RR, Jovančićević V, Podlavicki M. Optical and electrochemical study of underpotential deposition of bismuth on gold electrode. in Electrochimica Acta. 1980;25(9):1143-1146.
doi:10.1016/0013-4686(80)87111-8 .
Adžić, Radoslav R., Jovančićević, V., Podlavicki, M.M., "Optical and electrochemical study of underpotential deposition of bismuth on gold electrode" in Electrochimica Acta, 25, no. 9 (1980):1143-1146,
https://doi.org/10.1016/0013-4686(80)87111-8 . .

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