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The role of spin states in the catalytic mechanism of the intra- and extradiol cleavage of catechols by O-2
(Royal Soc Chemistry, Cambridge, 2017)
Iron-dependent enzymes and biomimetic iron complexes can catalyze the ring cleavage of very inert, aromatic compounds. The mechanisms of these transformations and the factors that lead either to extradiol cleavage or ...
Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
(Wiley-V C H Verlag Gmbh, Weinheim, 2015)
A series of heteropentanuclear oxalate-bridged Ru(NO)-Ln (4d-4f) metal complexes of the general formula (nBu(4)N)(5)[Ln{RuCl3(-ox)(NO)}(4)], where Ln=Y (2), Gd (3), Tb (4), Dy (5) and ox=oxalate anion, were obtained by ...
Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?
(Switzerland : Frontiers Media S.A., 2019)
In this work we use chemical fingerprints as characteristics ratios of specific crustal elements Ca/Al, Fe/Al, K/Al, Mg/Al, Mn/Al, Ca/Fe, and Mg/Fe to investigate the long-range transport of volcanic aerosols from Iceland. ...
Tunable invisibility cloaking by using isolated graphene-coated nanowires and dimers
(England : Nature Publishing Group, 2017)
We investigate, both theoretically and numerically, a graphene-coated nano-cylinder illuminated by a plane electromagnetic wave in the far-infrared range of frequencies. We have derived an analytical formula that enables ...
SEM/EDX and XRD characterization of silver nanocrystalline thin film prepared from organometallic solution precursor
(Technical Faculty, Bor-Serbia, Bor, 2013)
The Ag nano-structured thin films prepared on flat glass substrates have been studied. The ball-like silver nanoparticles have been synthesized in large quantity by using a modified method of hydrolytic decomposition of ...
Neuroprotective arylpiperazine dopaminergic/serotonergic ligands suppress experimental autoimmune encephalomyelitis in rats
(Wiley, Hoboken, 2015)
Arylpiperazine-based dopaminergic/serotonergic ligands exert neuroprotective activity. We examined the effect of arylpiperazine D-2/5-HT1A ligands, N-{4-[2-(4-phenyl-piperazin-1-yl)-ethyl}-phenyl]- picolinamide (6a) and ...
Synthesis, Characterization, and Cytotoxicity of a Novel Gold(III) Complex with O,O-Diethyl Ester of Ethylenediamine-N,N-Di-2-(4-Methyl)Pentanoic Acid
(MDPI, 2016)
A novel gold(III) complex, [AuCl2{(S,S)-Et(2)eddl}]PF6, ((S,S)-Et(2)eddl = O,O-diethyl ester of ethylenediamine-N,N-di-2-(4-methyl)pentanoic acid) was synthesized and characterized by IR, 1D (H-1 and C-13), and 2D (H,H-COSY ...
Magnetic and electric control of spin- and valley-polarized transport across tunnel junctions on monolayer WSe2
(Amer Physical Soc, College Pk, 2017)
The recent experimental realization of high-quality WSe2 leads to the possibility of an efficient manipulation of its spin and valley degrees of freedom. Its electronic properties comprise a huge spin-orbit coupling, a ...
Integer quantum Hall effect in gapped single-layer graphene
(Amer Physical Soc, College Pk, 2012)
Analytical expressions for the Hall conductivity sigma(yx) and the longitudinal resistivity rho(xx) are derived in gapped, single-layer graphene using linear response theory. The gap 2 Delta, described by a mass term, is ...
Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes
(Wiley-V C H Verlag Gmbh, Weinheim, 2018)
The complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square ...