Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials

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Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (en)
Authors

Publications

Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye

Ognjanović, Miloš; Stanković, Dalibor; Fabián, Martin; Vranješ-Đurić, Sanja; Antić, Bratislav; Dojčinović, Biljana

(IOP Publishing, 2020)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Fabián, Martin
AU  - Vranješ-Đurić, Sanja
AU  - Antić, Bratislav
AU  - Dojčinović, Biljana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3390
AB  - Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants.
PB  - IOP Publishing
T2  - Materials Research Express
T1  - Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye
VL  - 7
IS  - 1
SP  - 015509
DO  - 10.1088/2053-1591/ab6490
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor and Fabián, Martin and Vranješ-Đurić, Sanja and Antić, Bratislav and Dojčinović, Biljana",
year = "2020",
abstract = "Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants.",
publisher = "IOP Publishing",
journal = "Materials Research Express",
title = "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye",
volume = "7",
number = "1",
pages = "015509",
doi = "10.1088/2053-1591/ab6490"
}
Ognjanović, M., Stanković, D., Fabián, M., Vranješ-Đurić, S., Antić, B.,& Dojčinović, B.. (2020). Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express
IOP Publishing., 7(1), 015509.
https://doi.org/10.1088/2053-1591/ab6490
Ognjanović M, Stanković D, Fabián M, Vranješ-Đurić S, Antić B, Dojčinović B. Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express. 2020;7(1):015509.
doi:10.1088/2053-1591/ab6490 .
Ognjanović, Miloš, Stanković, Dalibor, Fabián, Martin, Vranješ-Đurić, Sanja, Antić, Bratislav, Dojčinović, Biljana, "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye" in Materials Research Express, 7, no. 1 (2020):015509,
https://doi.org/10.1088/2053-1591/ab6490 . .
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Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species

Dojčinović, Biljana; Jančar, Boštjan; Bessais, Lotfi; Kremenović, Aleksandar; Jović-Jovičić, Nataša; Banković, Predrag; Stanković, Dalibor; Ognjanović, Miloš; Antić, Bratislav

(IOP Publishing, 2019)

TY  - JOUR
AU  - Dojčinović, Biljana
AU  - Jančar, Boštjan
AU  - Bessais, Lotfi
AU  - Kremenović, Aleksandar
AU  - Jović-Jovičić, Nataša
AU  - Banković, Predrag
AU  - Stanković, Dalibor
AU  - Ognjanović, Miloš
AU  - Antić, Bratislav
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3243
AB  - Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3−x Y x O4 nanoparticles formed. The series of Fe3−x Y x O4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 °C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3−x Y x O4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO3 3−) and As(V) (arsenate, AsO4 3−), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t 1/2) of As(V) (Y00: pH 2–3, t 1/2 = 3.12 min; Y05: pH 2–6, t 1/2 = 2.12 min and Y10: pH 2–10, t 1/2 = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.
PB  - IOP Publishing
T2  - Nanotechnology
T1  - Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species
VL  - 30
IS  - 47
SP  - 475702
DO  - 10.1088/1361-6528/ab3ca2
ER  - 
@article{
author = "Dojčinović, Biljana and Jančar, Boštjan and Bessais, Lotfi and Kremenović, Aleksandar and Jović-Jovičić, Nataša and Banković, Predrag and Stanković, Dalibor and Ognjanović, Miloš and Antić, Bratislav",
year = "2019",
abstract = "Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3−x Y x O4 nanoparticles formed. The series of Fe3−x Y x O4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 °C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3−x Y x O4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO3 3−) and As(V) (arsenate, AsO4 3−), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t 1/2) of As(V) (Y00: pH 2–3, t 1/2 = 3.12 min; Y05: pH 2–6, t 1/2 = 2.12 min and Y10: pH 2–10, t 1/2 = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.",
publisher = "IOP Publishing",
journal = "Nanotechnology",
title = "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species",
volume = "30",
number = "47",
pages = "475702",
doi = "10.1088/1361-6528/ab3ca2"
}
Dojčinović, B., Jančar, B., Bessais, L., Kremenović, A., Jović-Jovičić, N., Banković, P., Stanković, D., Ognjanović, M.,& Antić, B.. (2019). Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology
IOP Publishing., 30(47), 475702.
https://doi.org/10.1088/1361-6528/ab3ca2
Dojčinović B, Jančar B, Bessais L, Kremenović A, Jović-Jovičić N, Banković P, Stanković D, Ognjanović M, Antić B. Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology. 2019;30(47):475702.
doi:10.1088/1361-6528/ab3ca2 .
Dojčinović, Biljana, Jančar, Boštjan, Bessais, Lotfi, Kremenović, Aleksandar, Jović-Jovičić, Nataša, Banković, Predrag, Stanković, Dalibor, Ognjanović, Miloš, Antić, Bratislav, "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species" in Nanotechnology, 30, no. 47 (2019):475702,
https://doi.org/10.1088/1361-6528/ab3ca2 . .
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Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species

Dojčinović, Biljana; Jančar, Boštjan; Bessais, Lotfi; Kremenović, Aleksandar; Jović-Jovičić, Nataša; Banković, Predrag; Stanković, Dalibor; Ognjanović, Miloš; Antić, Bratislav

(IOP Publishing, 2019)

TY  - JOUR
AU  - Dojčinović, Biljana
AU  - Jančar, Boštjan
AU  - Bessais, Lotfi
AU  - Kremenović, Aleksandar
AU  - Jović-Jovičić, Nataša
AU  - Banković, Predrag
AU  - Stanković, Dalibor
AU  - Ognjanović, Miloš
AU  - Antić, Bratislav
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3244
AB  - Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3−x Y x O4 nanoparticles formed. The series of Fe3−x Y x O4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 °C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3−x Y x O4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO3 3−) and As(V) (arsenate, AsO4 3−), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t 1/2) of As(V) (Y00: pH 2–3, t 1/2 = 3.12 min; Y05: pH 2–6, t 1/2 = 2.12 min and Y10: pH 2–10, t 1/2 = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.
PB  - IOP Publishing
T2  - Nanotechnology
T1  - Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species
VL  - 30
IS  - 47
SP  - 475702
DO  - 10.1088/1361-6528/ab3ca2
ER  - 
@article{
author = "Dojčinović, Biljana and Jančar, Boštjan and Bessais, Lotfi and Kremenović, Aleksandar and Jović-Jovičić, Nataša and Banković, Predrag and Stanković, Dalibor and Ognjanović, Miloš and Antić, Bratislav",
year = "2019",
abstract = "Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3−x Y x O4 nanoparticles formed. The series of Fe3−x Y x O4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 °C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3−x Y x O4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO3 3−) and As(V) (arsenate, AsO4 3−), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t 1/2) of As(V) (Y00: pH 2–3, t 1/2 = 3.12 min; Y05: pH 2–6, t 1/2 = 2.12 min and Y10: pH 2–10, t 1/2 = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.",
publisher = "IOP Publishing",
journal = "Nanotechnology",
title = "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species",
volume = "30",
number = "47",
pages = "475702",
doi = "10.1088/1361-6528/ab3ca2"
}
Dojčinović, B., Jančar, B., Bessais, L., Kremenović, A., Jović-Jovičić, N., Banković, P., Stanković, D., Ognjanović, M.,& Antić, B.. (2019). Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology
IOP Publishing., 30(47), 475702.
https://doi.org/10.1088/1361-6528/ab3ca2
Dojčinović B, Jančar B, Bessais L, Kremenović A, Jović-Jovičić N, Banković P, Stanković D, Ognjanović M, Antić B. Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology. 2019;30(47):475702.
doi:10.1088/1361-6528/ab3ca2 .
Dojčinović, Biljana, Jančar, Boštjan, Bessais, Lotfi, Kremenović, Aleksandar, Jović-Jovičić, Nataša, Banković, Predrag, Stanković, Dalibor, Ognjanović, Miloš, Antić, Bratislav, "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species" in Nanotechnology, 30, no. 47 (2019):475702,
https://doi.org/10.1088/1361-6528/ab3ca2 . .
5
2
5

Biliverdin-copper complex at physiological pH

Dimitrijević, Milena S.; Bogdanović Pristov, Jelena; Žižić, Milan; Stanković, Dalibor; Bajuk-Bogdanović, Danica; Stanić, Marina; Spasić, Snežana; Hagen, Wilfred; Spasojević, Ivan

(2019)

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor
AU  - Bajuk-Bogdanović, Danica
AU  - Stanić, Marina
AU  - Spasić, Snežana
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2932
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 
@article{
author = "Dimitrijević, Milena S. and Bogdanović Pristov, Jelena and Žižić, Milan and Stanković, Dalibor and Bajuk-Bogdanović, Danica and Stanić, Marina and Spasić, Snežana and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}
Dimitrijević, M. S., Bogdanović Pristov, J., Žižić, M., Stanković, D., Bajuk-Bogdanović, D., Stanić, M., Spasić, S., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c
Dimitrijević MS, Bogdanović Pristov J, Žižić M, Stanković D, Bajuk-Bogdanović D, Stanić M, Spasić S, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .
Dimitrijević, Milena S., Bogdanović Pristov, Jelena, Žižić, Milan, Stanković, Dalibor, Bajuk-Bogdanović, Danica, Stanić, Marina, Spasić, Snežana, Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .
10
6
9

Biliverdin-copper complex at physiological pH

Dimitrijević, Milena S.; Bogdanović Pristov, Jelena; Žižić, Milan; Stanković, Dalibor; Bajuk-Bogdanović, Danica; Stanić, Marina; Spasić, Snežana; Hagen, Wilfred; Spasojević, Ivan

(2019)

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor
AU  - Bajuk-Bogdanović, Danica
AU  - Stanić, Marina
AU  - Spasić, Snežana
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2933
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 
@article{
author = "Dimitrijević, Milena S. and Bogdanović Pristov, Jelena and Žižić, Milan and Stanković, Dalibor and Bajuk-Bogdanović, Danica and Stanić, Marina and Spasić, Snežana and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}
Dimitrijević, M. S., Bogdanović Pristov, J., Žižić, M., Stanković, D., Bajuk-Bogdanović, D., Stanić, M., Spasić, S., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c
Dimitrijević MS, Bogdanović Pristov J, Žižić M, Stanković D, Bajuk-Bogdanović D, Stanić M, Spasić S, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .
Dimitrijević, Milena S., Bogdanović Pristov, Jelena, Žižić, Milan, Stanković, Dalibor, Bajuk-Bogdanović, Danica, Stanić, Marina, Spasić, Snežana, Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .
10
6
9

Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay

Jović-Jovičić, Nataša; Mojović, Miloš; Stanković, Dalibor; Nedić-Vasiljević, Bojana; Milutinović Nikolić, Aleksandra; Banković, Predrag; Mojović, Zorica

(Oxford : Pergamon-Elsevier Science Ltd, 2019)

TY  - JOUR
AU  - Jović-Jovičić, Nataša
AU  - Mojović, Miloš
AU  - Stanković, Dalibor
AU  - Nedić-Vasiljević, Bojana
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
AU  - Mojović, Zorica
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2507
AB  - Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pH(PZC)), N-2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA(+) into interlamellar space of smectite. Series of carbonized clays showed constant d(001) value of 1.4 nm. The pH(PZC) of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA(+) loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Electrochimica Acta
T1  - Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay
VL  - 296
SP  - 387
EP  - 396
DO  - 10.1016/j.electacta.2018.11.031
ER  - 
@article{
author = "Jović-Jovičić, Nataša and Mojović, Miloš and Stanković, Dalibor and Nedić-Vasiljević, Bojana and Milutinović Nikolić, Aleksandra and Banković, Predrag and Mojović, Zorica",
year = "2019",
abstract = "Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pH(PZC)), N-2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA(+) into interlamellar space of smectite. Series of carbonized clays showed constant d(001) value of 1.4 nm. The pH(PZC) of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA(+) loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Electrochimica Acta",
title = "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay",
volume = "296",
pages = "387-396",
doi = "10.1016/j.electacta.2018.11.031"
}
Jović-Jovičić, N., Mojović, M., Stanković, D., Nedić-Vasiljević, B., Milutinović Nikolić, A., Banković, P.,& Mojović, Z.. (2019). Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta
Oxford : Pergamon-Elsevier Science Ltd., 296, 387-396.
https://doi.org/10.1016/j.electacta.2018.11.031
Jović-Jovičić N, Mojović M, Stanković D, Nedić-Vasiljević B, Milutinović Nikolić A, Banković P, Mojović Z. Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta. 2019;296:387-396.
doi:10.1016/j.electacta.2018.11.031 .
Jović-Jovičić, Nataša, Mojović, Miloš, Stanković, Dalibor, Nedić-Vasiljević, Bojana, Milutinović Nikolić, Aleksandra, Banković, Predrag, Mojović, Zorica, "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay" in Electrochimica Acta, 296 (2019):387-396,
https://doi.org/10.1016/j.electacta.2018.11.031 . .
7
5
8

Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay

Jović-Jovičić, Nataša; Mojović, Miloš; Stanković, Dalibor; Nedić-Vasiljević, Bojana; Milutinović Nikolić, Aleksandra; Banković, Predrag; Mojović, Zorica

(Oxford : Pergamon-Elsevier Science Ltd, 2019)

TY  - JOUR
AU  - Jović-Jovičić, Nataša
AU  - Mojović, Miloš
AU  - Stanković, Dalibor
AU  - Nedić-Vasiljević, Bojana
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
AU  - Mojović, Zorica
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2507
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2625
AB  - Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pH(PZC)), N-2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA(+) into interlamellar space of smectite. Series of carbonized clays showed constant d(001) value of 1.4 nm. The pH(PZC) of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA(+) loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Electrochimica Acta
T1  - Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay
VL  - 296
SP  - 387
EP  - 396
DO  - 10.1016/j.electacta.2018.11.031
ER  - 
@article{
author = "Jović-Jovičić, Nataša and Mojović, Miloš and Stanković, Dalibor and Nedić-Vasiljević, Bojana and Milutinović Nikolić, Aleksandra and Banković, Predrag and Mojović, Zorica",
year = "2019",
abstract = "Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pH(PZC)), N-2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA(+) into interlamellar space of smectite. Series of carbonized clays showed constant d(001) value of 1.4 nm. The pH(PZC) of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA(+) loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Electrochimica Acta",
title = "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay",
volume = "296",
pages = "387-396",
doi = "10.1016/j.electacta.2018.11.031"
}
Jović-Jovičić, N., Mojović, M., Stanković, D., Nedić-Vasiljević, B., Milutinović Nikolić, A., Banković, P.,& Mojović, Z.. (2019). Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta
Oxford : Pergamon-Elsevier Science Ltd., 296, 387-396.
https://doi.org/10.1016/j.electacta.2018.11.031
Jović-Jovičić N, Mojović M, Stanković D, Nedić-Vasiljević B, Milutinović Nikolić A, Banković P, Mojović Z. Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta. 2019;296:387-396.
doi:10.1016/j.electacta.2018.11.031 .
Jović-Jovičić, Nataša, Mojović, Miloš, Stanković, Dalibor, Nedić-Vasiljević, Bojana, Milutinović Nikolić, Aleksandra, Banković, Predrag, Mojović, Zorica, "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay" in Electrochimica Acta, 296 (2019):387-396,
https://doi.org/10.1016/j.electacta.2018.11.031 . .
7
5
8

Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia

Ognjanović, Miloš; Stanković, Dalibor; Ming, Y.; Zhang, H.; Jančar, Boštjan; Dojčinović, Biljana; Prijović, Željko; Antić, Bratislav

(Elsevier, 2019)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Ming, Y.
AU  - Zhang, H.
AU  - Jančar, Boštjan
AU  - Dojčinović, Biljana
AU  - Prijović, Željko
AU  - Antić, Bratislav
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2501
AB  - In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia
SP  - 454
EP  - 462
DO  - 10.1016/j.jallcom.2018.10.369
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor and Ming, Y. and Zhang, H. and Jančar, Boštjan and Dojčinović, Biljana and Prijović, Željko and Antić, Bratislav",
year = "2019",
abstract = "In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia",
pages = "454-462",
doi = "10.1016/j.jallcom.2018.10.369"
}
Ognjanović, M., Stanković, D., Ming, Y., Zhang, H., Jančar, B., Dojčinović, B., Prijović, Ž.,& Antić, B.. (2019). Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds
Elsevier., 454-462.
https://doi.org/10.1016/j.jallcom.2018.10.369
Ognjanović M, Stanković D, Ming Y, Zhang H, Jančar B, Dojčinović B, Prijović Ž, Antić B. Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds. 2019;:454-462.
doi:10.1016/j.jallcom.2018.10.369 .
Ognjanović, Miloš, Stanković, Dalibor, Ming, Y., Zhang, H., Jančar, Boštjan, Dojčinović, Biljana, Prijović, Željko, Antić, Bratislav, "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia" in Journal of Alloys and Compounds (2019):454-462,
https://doi.org/10.1016/j.jallcom.2018.10.369 . .
28
15
26

Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia

Ognjanović, Miloš; Stanković, Dalibor; Ming, Y.; Zhang, H.; Jančar, Boštjan; Dojčinović, Biljana; Prijović, Željko; Antić, Bratislav

(Elsevier, 2019)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Ming, Y.
AU  - Zhang, H.
AU  - Jančar, Boštjan
AU  - Dojčinović, Biljana
AU  - Prijović, Željko
AU  - Antić, Bratislav
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2501
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2624
AB  - In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia
SP  - 454
EP  - 462
DO  - 10.1016/j.jallcom.2018.10.369
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor and Ming, Y. and Zhang, H. and Jančar, Boštjan and Dojčinović, Biljana and Prijović, Željko and Antić, Bratislav",
year = "2019",
abstract = "In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia",
pages = "454-462",
doi = "10.1016/j.jallcom.2018.10.369"
}
Ognjanović, M., Stanković, D., Ming, Y., Zhang, H., Jančar, B., Dojčinović, B., Prijović, Ž.,& Antić, B.. (2019). Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds
Elsevier., 454-462.
https://doi.org/10.1016/j.jallcom.2018.10.369
Ognjanović M, Stanković D, Ming Y, Zhang H, Jančar B, Dojčinović B, Prijović Ž, Antić B. Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds. 2019;:454-462.
doi:10.1016/j.jallcom.2018.10.369 .
Ognjanović, Miloš, Stanković, Dalibor, Ming, Y., Zhang, H., Jančar, Boštjan, Dojčinović, Biljana, Prijović, Željko, Antić, Bratislav, "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia" in Journal of Alloys and Compounds (2019):454-462,
https://doi.org/10.1016/j.jallcom.2018.10.369 . .
28
15
26

Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach

Stanković, Dalibor; Ognjanović, Miloš; Espinosa, Ana; del Puerto Morales, Maria; Bessais, Lotfi; Zehani, Karim; Antić, Bratislav; Dojčinović, Biljana

(Springer Science and Business Media LLC, 2019)

TY  - JOUR
AU  - Stanković, Dalibor
AU  - Ognjanović, Miloš
AU  - Espinosa, Ana
AU  - del Puerto Morales, Maria
AU  - Bessais, Lotfi
AU  - Zehani, Karim
AU  - Antić, Bratislav
AU  - Dojčinović, Biljana
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3250
AB  - In this study, for the first time, we developed a novel platform for the removal of the synthetic organic dye Reactive Blue 52 based on a screen-printed electrode (SPCE). Additionally, SPCE was supported on a nanocomposite obtained by decoration of reduced graphene oxide (RGO) with iron oxide nanoflowers (IONFs), labeled as IONF@RGO/SPCE. IONFs were synthesized by polyol-mediated reduction of iron (III) chloride and characterized. Nanocomposite was prepared using a microwave hydrothermal-assisted procedure. The high stability (service life) of the IONF@RGO/SPCE electrode was measured, and it remained almost unchanged over time, achieving the same removal efficiency after 50 cycles of usage. Electrical impedance spectroscopy (EIS) tests indicated the synergetic effect of the used IONF@RGO by reducing resistivity of the system and improving its catalytic activity, which was confirmed with cyclic voltammetry (CV tests) where the great increase of the electrochemically active surface area sites was obvious. The results clearly indicate that with this approach, the optimum removal time of the selected pollutant was only 30 min, at a working potential of 3 V and with potassium chloride as the supporting electrolyte, with color removal efficiency of 99%, while chemical oxygen demand (COD) of more than 40%, total organic carbon (TOC) decrease of around 20%, and biochemical oxygen demand (BOD5), i.e., biodegradability (BOD5/COD ratio) significantly increased were measured after only 1 h of the treatment. Overall, the electrochemical removal procedure proposed in this study could be a reliable novel system, opening a new approach to using screen print–based electrodes.
PB  - Springer Science and Business Media LLC
T2  - Electrocatalysis
T1  - Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach
VL  - 10
IS  - 6
SP  - 663
EP  - 671
DO  - 10.1007/s12678-019-00554-1
ER  - 
@article{
author = "Stanković, Dalibor and Ognjanović, Miloš and Espinosa, Ana and del Puerto Morales, Maria and Bessais, Lotfi and Zehani, Karim and Antić, Bratislav and Dojčinović, Biljana",
year = "2019",
abstract = "In this study, for the first time, we developed a novel platform for the removal of the synthetic organic dye Reactive Blue 52 based on a screen-printed electrode (SPCE). Additionally, SPCE was supported on a nanocomposite obtained by decoration of reduced graphene oxide (RGO) with iron oxide nanoflowers (IONFs), labeled as IONF@RGO/SPCE. IONFs were synthesized by polyol-mediated reduction of iron (III) chloride and characterized. Nanocomposite was prepared using a microwave hydrothermal-assisted procedure. The high stability (service life) of the IONF@RGO/SPCE electrode was measured, and it remained almost unchanged over time, achieving the same removal efficiency after 50 cycles of usage. Electrical impedance spectroscopy (EIS) tests indicated the synergetic effect of the used IONF@RGO by reducing resistivity of the system and improving its catalytic activity, which was confirmed with cyclic voltammetry (CV tests) where the great increase of the electrochemically active surface area sites was obvious. The results clearly indicate that with this approach, the optimum removal time of the selected pollutant was only 30 min, at a working potential of 3 V and with potassium chloride as the supporting electrolyte, with color removal efficiency of 99%, while chemical oxygen demand (COD) of more than 40%, total organic carbon (TOC) decrease of around 20%, and biochemical oxygen demand (BOD5), i.e., biodegradability (BOD5/COD ratio) significantly increased were measured after only 1 h of the treatment. Overall, the electrochemical removal procedure proposed in this study could be a reliable novel system, opening a new approach to using screen print–based electrodes.",
publisher = "Springer Science and Business Media LLC",
journal = "Electrocatalysis",
title = "Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach",
volume = "10",
number = "6",
pages = "663-671",
doi = "10.1007/s12678-019-00554-1"
}
Stanković, D., Ognjanović, M., Espinosa, A., del Puerto Morales, M., Bessais, L., Zehani, K., Antić, B.,& Dojčinović, B.. (2019). Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach. in Electrocatalysis
Springer Science and Business Media LLC., 10(6), 663-671.
https://doi.org/10.1007/s12678-019-00554-1
Stanković D, Ognjanović M, Espinosa A, del Puerto Morales M, Bessais L, Zehani K, Antić B, Dojčinović B. Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach. in Electrocatalysis. 2019;10(6):663-671.
doi:10.1007/s12678-019-00554-1 .
Stanković, Dalibor, Ognjanović, Miloš, Espinosa, Ana, del Puerto Morales, Maria, Bessais, Lotfi, Zehani, Karim, Antić, Bratislav, Dojčinović, Biljana, "Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach" in Electrocatalysis, 10, no. 6 (2019):663-671,
https://doi.org/10.1007/s12678-019-00554-1 . .
15
7
14

Polyurethane/ferrite nanocomposites: preparation and physical properties

Kodranov, Igor; Dojčinović, Biljana; Antić, Bratislav; Manojlović, Dragan; Ognjanović, Miloš; Pergal, Marija

(Society of Physical Chemists of Serbia, 2018)

TY  - CONF
AU  - Kodranov, Igor
AU  - Dojčinović, Biljana
AU  - Antić, Bratislav
AU  - Manojlović, Dragan
AU  - Ognjanović, Miloš
AU  - Pergal, Marija
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5812
AB  - In the present study, polyurethane/ferrite composites (PU-NFs) were prepared using silver ferrite, copper ferrite and zinc ferrite (1 wt.%) by in situ two-step polymerization in solution. PU-NFs based on poly(dimethylsiloxane) as soft segment and hyperbranched polyester of the second pseudo generation/4,4'-methylenediphenyl diisocyanate as the hard segment were prepared with constant soft segment content (60 wt.%). The prepared PU-NFs and PU network (sample without nanoferrites) were characterized by FTIR, DSC and TG analyses. The glass transition of the hard segment (TgHS) of PU-NFs was similar to TgHS value of the unfilled PU network. The results showed that PU-NFs had better thermal stability than pure PU network.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - Physical Chemistry 2018 - 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018, Belgrade
T1  - Polyurethane/ferrite nanocomposites: preparation and physical properties
VL  - 2
SP  - 617
EP  - 620
UR  - https://hdl.handle.net/21.15107/rcub_cer_5812
ER  - 
@conference{
author = "Kodranov, Igor and Dojčinović, Biljana and Antić, Bratislav and Manojlović, Dragan and Ognjanović, Miloš and Pergal, Marija",
year = "2018",
abstract = "In the present study, polyurethane/ferrite composites (PU-NFs) were prepared using silver ferrite, copper ferrite and zinc ferrite (1 wt.%) by in situ two-step polymerization in solution. PU-NFs based on poly(dimethylsiloxane) as soft segment and hyperbranched polyester of the second pseudo generation/4,4'-methylenediphenyl diisocyanate as the hard segment were prepared with constant soft segment content (60 wt.%). The prepared PU-NFs and PU network (sample without nanoferrites) were characterized by FTIR, DSC and TG analyses. The glass transition of the hard segment (TgHS) of PU-NFs was similar to TgHS value of the unfilled PU network. The results showed that PU-NFs had better thermal stability than pure PU network.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - Physical Chemistry 2018 - 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018, Belgrade",
title = "Polyurethane/ferrite nanocomposites: preparation and physical properties",
volume = "2",
pages = "617-620",
url = "https://hdl.handle.net/21.15107/rcub_cer_5812"
}
Kodranov, I., Dojčinović, B., Antić, B., Manojlović, D., Ognjanović, M.,& Pergal, M.. (2018). Polyurethane/ferrite nanocomposites: preparation and physical properties. in Proceedings - Physical Chemistry 2018 - 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018, Belgrade
Society of Physical Chemists of Serbia., 2, 617-620.
https://hdl.handle.net/21.15107/rcub_cer_5812
Kodranov I, Dojčinović B, Antić B, Manojlović D, Ognjanović M, Pergal M. Polyurethane/ferrite nanocomposites: preparation and physical properties. in Proceedings - Physical Chemistry 2018 - 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018, Belgrade. 2018;2:617-620.
https://hdl.handle.net/21.15107/rcub_cer_5812 .
Kodranov, Igor, Dojčinović, Biljana, Antić, Bratislav, Manojlović, Dragan, Ognjanović, Miloš, Pergal, Marija, "Polyurethane/ferrite nanocomposites: preparation and physical properties" in Proceedings - Physical Chemistry 2018 - 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry, September 24-28, 2018, Belgrade, 2 (2018):617-620,
https://hdl.handle.net/21.15107/rcub_cer_5812 .

Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties

Pergal, Marija; Balaban, Milica; Stanković, Dalibor; Petković, Branka B.

(Nova Science, 2018)

TY  - CHAP
AU  - Pergal, Marija
AU  - Balaban, Milica
AU  - Stanković, Dalibor
AU  - Petković, Branka B.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2404
AB  - Poly(dimethylsiloxane)s (PDMS) have one of the lowest values of glass transition temperature among synthetic polymers, and indicate lowtemperature flexibility, excellent thermal, thermo-oxidative and ultraviolet stability, very low surface energy, high hydrophobicity, high gas permeability and good biocompatibility. α,ω-Difunctionalized (or telechelic) PDMSs of low molecular weights are various starting prepolymers for the preparation of a wide variety of types of PDMSbased segmented copolymers, such as polyurethanes, polyesters, polyamides and polyimides, as well as for the preparation of polymer networks such as epoxy and polyurethane networks. Polymers based on PDMS which combine the specific and unique properties of PDMS with the mechanical strength of organic segments have a wide range of important applications such as elastomers, protective coatings, surfactants, gas separation membranes, photoresists, contact lenses and biomaterials. This chapter surveys the most relevant aspects related to the synthesis, structure and physical properties of PDMS modified segmented copolymers and polymer networks. Influence of the structure and molecular weight of PDMS prepolymers and organic segments on the morphology and properties of the copolymers and polymer networks based on PDMS is discussed. Correlation between composition and microstructure-property behavior of PDMS-based copolymers and polymer networks will be reported in detail. This chapter also discusses PDMS-based blends and reinforcement of PDMS-based copolymers via addition of nanoparticle-based materials and characterization of these PDMS-based blends and nanocomposites. The potential application of PDMS-based materials and future trends in chemistry and synthesis of PDMS-based copolymers and polymer networks will also be given.
PB  - Nova Science
T2  - Advances in Chemistry Research
T1  - Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties
VL  - 43
SP  - 1
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_cer_2404
ER  - 
@inbook{
author = "Pergal, Marija and Balaban, Milica and Stanković, Dalibor and Petković, Branka B.",
year = "2018",
abstract = "Poly(dimethylsiloxane)s (PDMS) have one of the lowest values of glass transition temperature among synthetic polymers, and indicate lowtemperature flexibility, excellent thermal, thermo-oxidative and ultraviolet stability, very low surface energy, high hydrophobicity, high gas permeability and good biocompatibility. α,ω-Difunctionalized (or telechelic) PDMSs of low molecular weights are various starting prepolymers for the preparation of a wide variety of types of PDMSbased segmented copolymers, such as polyurethanes, polyesters, polyamides and polyimides, as well as for the preparation of polymer networks such as epoxy and polyurethane networks. Polymers based on PDMS which combine the specific and unique properties of PDMS with the mechanical strength of organic segments have a wide range of important applications such as elastomers, protective coatings, surfactants, gas separation membranes, photoresists, contact lenses and biomaterials. This chapter surveys the most relevant aspects related to the synthesis, structure and physical properties of PDMS modified segmented copolymers and polymer networks. Influence of the structure and molecular weight of PDMS prepolymers and organic segments on the morphology and properties of the copolymers and polymer networks based on PDMS is discussed. Correlation between composition and microstructure-property behavior of PDMS-based copolymers and polymer networks will be reported in detail. This chapter also discusses PDMS-based blends and reinforcement of PDMS-based copolymers via addition of nanoparticle-based materials and characterization of these PDMS-based blends and nanocomposites. The potential application of PDMS-based materials and future trends in chemistry and synthesis of PDMS-based copolymers and polymer networks will also be given.",
publisher = "Nova Science",
journal = "Advances in Chemistry Research",
booktitle = "Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties",
volume = "43",
pages = "1-80",
url = "https://hdl.handle.net/21.15107/rcub_cer_2404"
}
Pergal, M., Balaban, M., Stanković, D.,& Petković, B. B.. (2018). Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties. in Advances in Chemistry Research
Nova Science., 43, 1-80.
https://hdl.handle.net/21.15107/rcub_cer_2404
Pergal M, Balaban M, Stanković D, Petković BB. Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties. in Advances in Chemistry Research. 2018;43:1-80.
https://hdl.handle.net/21.15107/rcub_cer_2404 .
Pergal, Marija, Balaban, Milica, Stanković, Dalibor, Petković, Branka B., "Poly(dimethylsiloxane) modified polymers: Synthesis, structure and physical properties" in Advances in Chemistry Research, 43 (2018):1-80,
https://hdl.handle.net/21.15107/rcub_cer_2404 .
2

Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity

Božić, Bojana; Korać, Jelena; Stanković, Dalibor; Stanić, Marina; Romanović, Mima; Bogdanović Pristov, Jelena; Spasić, Snežana; Popović-Bjelić, Ana; Spasojević, Ivan; Bajčetić, Milica

(Elsevier, 2018)

TY  - JOUR
AU  - Božić, Bojana
AU  - Korać, Jelena
AU  - Stanković, Dalibor
AU  - Stanić, Marina
AU  - Romanović, Mima
AU  - Bogdanović Pristov, Jelena
AU  - Spasić, Snežana
AU  - Popović-Bjelić, Ana
AU  - Spasojević, Ivan
AU  - Bajčetić, Milica
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3936
AB  - An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis.
PB  - Elsevier
T2  - Free Radical Biology and Medicine
T1  - Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity
VL  - 129
SP  - 279
EP  - 285
DO  - 10.1016/j.freeradbiomed.2018.09.038
ER  - 
@article{
author = "Božić, Bojana and Korać, Jelena and Stanković, Dalibor and Stanić, Marina and Romanović, Mima and Bogdanović Pristov, Jelena and Spasić, Snežana and Popović-Bjelić, Ana and Spasojević, Ivan and Bajčetić, Milica",
year = "2018",
abstract = "An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis.",
publisher = "Elsevier",
journal = "Free Radical Biology and Medicine",
title = "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity",
volume = "129",
pages = "279-285",
doi = "10.1016/j.freeradbiomed.2018.09.038"
}
Božić, B., Korać, J., Stanković, D., Stanić, M., Romanović, M., Bogdanović Pristov, J., Spasić, S., Popović-Bjelić, A., Spasojević, I.,& Bajčetić, M.. (2018). Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine
Elsevier., 129, 279-285.
https://doi.org/10.1016/j.freeradbiomed.2018.09.038
Božić B, Korać J, Stanković D, Stanić M, Romanović M, Bogdanović Pristov J, Spasić S, Popović-Bjelić A, Spasojević I, Bajčetić M. Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine. 2018;129:279-285.
doi:10.1016/j.freeradbiomed.2018.09.038 .
Božić, Bojana, Korać, Jelena, Stanković, Dalibor, Stanić, Marina, Romanović, Mima, Bogdanović Pristov, Jelena, Spasić, Snežana, Popović-Bjelić, Ana, Spasojević, Ivan, Bajčetić, Milica, "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity" in Free Radical Biology and Medicine, 129 (2018):279-285,
https://doi.org/10.1016/j.freeradbiomed.2018.09.038 . .
1
12
4
13

Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity

Božić, Bojana; Korać, Jelena; Stanković, Dalibor; Stanić, Marina; Romanović, Mima; Bogdanović Pristov, Jelena; Spasić, Snežana; Popović-Bjelić, Ana; Spasojević, Ivan; Bajčetić, Milica

(Elsevier, 2018)

TY  - JOUR
AU  - Božić, Bojana
AU  - Korać, Jelena
AU  - Stanković, Dalibor
AU  - Stanić, Marina
AU  - Romanović, Mima
AU  - Bogdanović Pristov, Jelena
AU  - Spasić, Snežana
AU  - Popović-Bjelić, Ana
AU  - Spasojević, Ivan
AU  - Bajčetić, Milica
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4281
AB  - An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis.
PB  - Elsevier
T2  - Free Radical Biology and Medicine
T1  - Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity
VL  - 129
SP  - 279
EP  - 285
DO  - 10.1016/j.freeradbiomed.2018.09.038
ER  - 
@article{
author = "Božić, Bojana and Korać, Jelena and Stanković, Dalibor and Stanić, Marina and Romanović, Mima and Bogdanović Pristov, Jelena and Spasić, Snežana and Popović-Bjelić, Ana and Spasojević, Ivan and Bajčetić, Milica",
year = "2018",
abstract = "An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis.",
publisher = "Elsevier",
journal = "Free Radical Biology and Medicine",
title = "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity",
volume = "129",
pages = "279-285",
doi = "10.1016/j.freeradbiomed.2018.09.038"
}
Božić, B., Korać, J., Stanković, D., Stanić, M., Romanović, M., Bogdanović Pristov, J., Spasić, S., Popović-Bjelić, A., Spasojević, I.,& Bajčetić, M.. (2018). Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine
Elsevier., 129, 279-285.
https://doi.org/10.1016/j.freeradbiomed.2018.09.038
Božić B, Korać J, Stanković D, Stanić M, Romanović M, Bogdanović Pristov J, Spasić S, Popović-Bjelić A, Spasojević I, Bajčetić M. Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine. 2018;129:279-285.
doi:10.1016/j.freeradbiomed.2018.09.038 .
Božić, Bojana, Korać, Jelena, Stanković, Dalibor, Stanić, Marina, Romanović, Mima, Bogdanović Pristov, Jelena, Spasić, Snežana, Popović-Bjelić, Ana, Spasojević, Ivan, Bajčetić, Milica, "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity" in Free Radical Biology and Medicine, 129 (2018):279-285,
https://doi.org/10.1016/j.freeradbiomed.2018.09.038 . .
1
12
4
12

Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity"

Božić, Bojana; Korać, Jelena; Stanković, Dalibor; Stanić, Marina; Romanović, Mima; Bogdanović Pristov, Jelena; Spasić, Snežana; Popović-Bjelić, Ana; Spasojević, Ivan; Bajčetić, Milica

(Elsevier, 2018)

TY  - DATA
AU  - Božić, Bojana
AU  - Korać, Jelena
AU  - Stanković, Dalibor
AU  - Stanić, Marina
AU  - Romanović, Mima
AU  - Bogdanović Pristov, Jelena
AU  - Spasić, Snežana
AU  - Popović-Bjelić, Ana
AU  - Spasojević, Ivan
AU  - Bajčetić, Milica
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4489
AB  - Figure S1. Speciation diagrams of Cu2+ in the phosphate buffer. Diagrams were prepared in Hydra-Medusa Software, using the presented parameters.
PB  - Elsevier
T2  - Free Radical Biology and Medicine
T1  - Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity"
UR  - https://hdl.handle.net/21.15107/rcub_cer_4489
ER  - 
@misc{
author = "Božić, Bojana and Korać, Jelena and Stanković, Dalibor and Stanić, Marina and Romanović, Mima and Bogdanović Pristov, Jelena and Spasić, Snežana and Popović-Bjelić, Ana and Spasojević, Ivan and Bajčetić, Milica",
year = "2018",
abstract = "Figure S1. Speciation diagrams of Cu2+ in the phosphate buffer. Diagrams were prepared in Hydra-Medusa Software, using the presented parameters.",
publisher = "Elsevier",
journal = "Free Radical Biology and Medicine",
title = "Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity"",
url = "https://hdl.handle.net/21.15107/rcub_cer_4489"
}
Božić, B., Korać, J., Stanković, D., Stanić, M., Romanović, M., Bogdanović Pristov, J., Spasić, S., Popović-Bjelić, A., Spasojević, I.,& Bajčetić, M.. (2018). Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity". in Free Radical Biology and Medicine
Elsevier..
https://hdl.handle.net/21.15107/rcub_cer_4489
Božić B, Korać J, Stanković D, Stanić M, Romanović M, Bogdanović Pristov J, Spasić S, Popović-Bjelić A, Spasojević I, Bajčetić M. Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity". in Free Radical Biology and Medicine. 2018;.
https://hdl.handle.net/21.15107/rcub_cer_4489 .
Božić, Bojana, Korać, Jelena, Stanković, Dalibor, Stanić, Marina, Romanović, Mima, Bogdanović Pristov, Jelena, Spasić, Snežana, Popović-Bjelić, Ana, Spasojević, Ivan, Bajčetić, Milica, "Supporting Information for: "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity"" in Free Radical Biology and Medicine (2018),
https://hdl.handle.net/21.15107/rcub_cer_4489 .

Determination of Total Antioxidant Capacity in Human Milk and Infant Formula

Lugonja, Nikoleta; Stanković, Dalibor; Milić, Jelena; Spasić, Snežana; Vrvić, Miroslav

(Vinča - Belgrade, Serbia : Vinča Institute of nuclear sciences, 2018)

TY  - CONF
AU  - Lugonja, Nikoleta
AU  - Stanković, Dalibor
AU  - Milić, Jelena
AU  - Spasić, Snežana
AU  - Vrvić, Miroslav
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4952
AB  - The object of this research was to investigate the total antioxidant capacity of human milk, human milk supplemented with fortifier and infant formula, by electrochemical and DPPH methods.
PB  - Vinča - Belgrade, Serbia : Vinča Institute of nuclear sciences
C3  - Proceedings - 6th Workshop Specific Methods for Food Safety and Quality
T1  - Determination of Total Antioxidant Capacity in Human Milk and Infant Formula
SP  - 41
EP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_cer_4952
ER  - 
@conference{
author = "Lugonja, Nikoleta and Stanković, Dalibor and Milić, Jelena and Spasić, Snežana and Vrvić, Miroslav",
year = "2018",
abstract = "The object of this research was to investigate the total antioxidant capacity of human milk, human milk supplemented with fortifier and infant formula, by electrochemical and DPPH methods.",
publisher = "Vinča - Belgrade, Serbia : Vinča Institute of nuclear sciences",
journal = "Proceedings - 6th Workshop Specific Methods for Food Safety and Quality",
title = "Determination of Total Antioxidant Capacity in Human Milk and Infant Formula",
pages = "41-44",
url = "https://hdl.handle.net/21.15107/rcub_cer_4952"
}
Lugonja, N., Stanković, D., Milić, J., Spasić, S.,& Vrvić, M.. (2018). Determination of Total Antioxidant Capacity in Human Milk and Infant Formula. in Proceedings - 6th Workshop Specific Methods for Food Safety and Quality
Vinča - Belgrade, Serbia : Vinča Institute of nuclear sciences., 41-44.
https://hdl.handle.net/21.15107/rcub_cer_4952
Lugonja N, Stanković D, Milić J, Spasić S, Vrvić M. Determination of Total Antioxidant Capacity in Human Milk and Infant Formula. in Proceedings - 6th Workshop Specific Methods for Food Safety and Quality. 2018;:41-44.
https://hdl.handle.net/21.15107/rcub_cer_4952 .
Lugonja, Nikoleta, Stanković, Dalibor, Milić, Jelena, Spasić, Snežana, Vrvić, Miroslav, "Determination of Total Antioxidant Capacity in Human Milk and Infant Formula" in Proceedings - 6th Workshop Specific Methods for Food Safety and Quality (2018):41-44,
https://hdl.handle.net/21.15107/rcub_cer_4952 .

A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone

Ognjanović, Miloš; Stanković, Dalibor; Fabian, Martin; Vukadinovic, Aleksandar; Prijovic, Zeljko; Dojčinović, Biljana; Antić, Bratislav

(Wiley-Blackwell, Malden, 2018)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Fabian, Martin
AU  - Vukadinovic, Aleksandar
AU  - Prijovic, Zeljko
AU  - Dojčinović, Biljana
AU  - Antić, Bratislav
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2354
AB  - In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe"RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are  LT = 0.31 mu M. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone
VL  - 30
IS  - 11
SP  - 2620
EP  - 2627
DO  - 10.1002/elan.201800357
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor and Fabian, Martin and Vukadinovic, Aleksandar and Prijovic, Zeljko and Dojčinović, Biljana and Antić, Bratislav",
year = "2018",
abstract = "In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe"RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are  LT = 0.31 mu M. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone",
volume = "30",
number = "11",
pages = "2620-2627",
doi = "10.1002/elan.201800357"
}
Ognjanović, M., Stanković, D., Fabian, M., Vukadinovic, A., Prijovic, Z., Dojčinović, B.,& Antić, B.. (2018). A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis
Wiley-Blackwell, Malden., 30(11), 2620-2627.
https://doi.org/10.1002/elan.201800357
Ognjanović M, Stanković D, Fabian M, Vukadinovic A, Prijovic Z, Dojčinović B, Antić B. A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis. 2018;30(11):2620-2627.
doi:10.1002/elan.201800357 .
Ognjanović, Miloš, Stanković, Dalibor, Fabian, Martin, Vukadinovic, Aleksandar, Prijovic, Zeljko, Dojčinović, Biljana, Antić, Bratislav, "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone" in Electroanalysis, 30, no. 11 (2018):2620-2627,
https://doi.org/10.1002/elan.201800357 . .
21
12
19

Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone"

Ognjanović, Miloš; Stanković, Dalibor; Fabian, Martin; Vukadinovic, Aleksandar; Prijovic, Zeljko; Dojčinović, Biljana; Antić, Bratislav

(Wiley-Blackwell, 2018)

TY  - DATA
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Fabian, Martin
AU  - Vukadinovic, Aleksandar
AU  - Prijovic, Zeljko
AU  - Dojčinović, Biljana
AU  - Antić, Bratislav
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4533
AB  - Fig. S1 Log-normal distribution function from fitting the TEM particle size data. Fig. S2 EDS mapping for MgFe@RGO composite. Fig. S3 CV voltammograms of: (A) different CC concentration in presence of constant HQ concentration in solution; (B) different HQ concentration in presence of constant CC concentration in solution; (C) different CC and HQ concentrations. Supporting electrolyte Ac-buffer, scan rate 100 mV/s. working electrode MgFe@RGO composite modified electrode. Fig. S4 CV voltammograms of CC and HQ at various scan rates in the range from 10 to 200 mV/s. Supporting electrolyte Ac-buffer, working electrode MgFe@RGO composite modified electrode. Dependence of peak currents and square root of the scan rate (inset). Fig. S5 DPV voltammogram in the presence of 0.1 mM of both analytes.
PB  - Wiley-Blackwell
T2  - Electroanalysis
T1  - Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone"
UR  - https://hdl.handle.net/21.15107/rcub_cer_4533
ER  - 
@misc{
author = "Ognjanović, Miloš and Stanković, Dalibor and Fabian, Martin and Vukadinovic, Aleksandar and Prijovic, Zeljko and Dojčinović, Biljana and Antić, Bratislav",
year = "2018",
abstract = "Fig. S1 Log-normal distribution function from fitting the TEM particle size data. Fig. S2 EDS mapping for MgFe@RGO composite. Fig. S3 CV voltammograms of: (A) different CC concentration in presence of constant HQ concentration in solution; (B) different HQ concentration in presence of constant CC concentration in solution; (C) different CC and HQ concentrations. Supporting electrolyte Ac-buffer, scan rate 100 mV/s. working electrode MgFe@RGO composite modified electrode. Fig. S4 CV voltammograms of CC and HQ at various scan rates in the range from 10 to 200 mV/s. Supporting electrolyte Ac-buffer, working electrode MgFe@RGO composite modified electrode. Dependence of peak currents and square root of the scan rate (inset). Fig. S5 DPV voltammogram in the presence of 0.1 mM of both analytes.",
publisher = "Wiley-Blackwell",
journal = "Electroanalysis",
title = "Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone"",
url = "https://hdl.handle.net/21.15107/rcub_cer_4533"
}
Ognjanović, M., Stanković, D., Fabian, M., Vukadinovic, A., Prijovic, Z., Dojčinović, B.,& Antić, B.. (2018). Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone". in Electroanalysis
Wiley-Blackwell..
https://hdl.handle.net/21.15107/rcub_cer_4533
Ognjanović M, Stanković D, Fabian M, Vukadinovic A, Prijovic Z, Dojčinović B, Antić B. Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone". in Electroanalysis. 2018;.
https://hdl.handle.net/21.15107/rcub_cer_4533 .
Ognjanović, Miloš, Stanković, Dalibor, Fabian, Martin, Vukadinovic, Aleksandar, Prijovic, Zeljko, Dojčinović, Biljana, Antić, Bratislav, "Supplementary material for: "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone"" in Electroanalysis (2018),
https://hdl.handle.net/21.15107/rcub_cer_4533 .

Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode

Đurđić, Slađana; Vukojević, Vesna; Jevtic, Sonja; Pergal, Marija; Petković, Branka B.; Stanković, Dalibor

(Esg, Belgrade, 2018)

TY  - JOUR
AU  - Đurđić, Slađana
AU  - Vukojević, Vesna
AU  - Jevtic, Sonja
AU  - Pergal, Marija
AU  - Petković, Branka B.
AU  - Stanković, Dalibor
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2340
AB  - In this work, for the first time we proposed electrochemical behavior and development of an analytical procedure for quantification of pesticide clomazone. Electrochemical behavior of clomazone's at boron-doped diamond electrode is characterized with irreversible oxidation at potential of around 1.6 V, in Britton-Robinson buffer solution at pH 2. It was found that potential of this oxidation was not pH dependent excluding presence of proton in the electrochemical reaction. Square wave voltammetry method was the most appropriate for clomazone quantification and proposed procedure was successfully applied for determination of clomazone in river water samples. Obtained parameters, detection limit of 0.21 mu M and working linear range from 1 to 100 mu M and satisfied selectivity can indicate that presented results open new field in research of this group of pesticides and offer possible replacement to the sophisticated and expensive chromatographic methods.
PB  - Esg, Belgrade
T2  - International Journal of Electrochemical Science
T1  - Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode
VL  - 13
IS  - 3
SP  - 2791
EP  - 2799
DO  - 10.20964/2018.03.39
ER  - 
@article{
author = "Đurđić, Slađana and Vukojević, Vesna and Jevtic, Sonja and Pergal, Marija and Petković, Branka B. and Stanković, Dalibor",
year = "2018",
abstract = "In this work, for the first time we proposed electrochemical behavior and development of an analytical procedure for quantification of pesticide clomazone. Electrochemical behavior of clomazone's at boron-doped diamond electrode is characterized with irreversible oxidation at potential of around 1.6 V, in Britton-Robinson buffer solution at pH 2. It was found that potential of this oxidation was not pH dependent excluding presence of proton in the electrochemical reaction. Square wave voltammetry method was the most appropriate for clomazone quantification and proposed procedure was successfully applied for determination of clomazone in river water samples. Obtained parameters, detection limit of 0.21 mu M and working linear range from 1 to 100 mu M and satisfied selectivity can indicate that presented results open new field in research of this group of pesticides and offer possible replacement to the sophisticated and expensive chromatographic methods.",
publisher = "Esg, Belgrade",
journal = "International Journal of Electrochemical Science",
title = "Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode",
volume = "13",
number = "3",
pages = "2791-2799",
doi = "10.20964/2018.03.39"
}
Đurđić, S., Vukojević, V., Jevtic, S., Pergal, M., Petković, B. B.,& Stanković, D.. (2018). Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode. in International Journal of Electrochemical Science
Esg, Belgrade., 13(3), 2791-2799.
https://doi.org/10.20964/2018.03.39
Đurđić S, Vukojević V, Jevtic S, Pergal M, Petković BB, Stanković D. Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode. in International Journal of Electrochemical Science. 2018;13(3):2791-2799.
doi:10.20964/2018.03.39 .
Đurđić, Slađana, Vukojević, Vesna, Jevtic, Sonja, Pergal, Marija, Petković, Branka B., Stanković, Dalibor, "Herbicide Clomazone Detection Using Electroanalytical Approach Using Boron Doped Diamond Electrode" in International Journal of Electrochemical Science, 13, no. 3 (2018):2791-2799,
https://doi.org/10.20964/2018.03.39 . .
9
5
12

First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach

Vukojević, Vesna; Đurđić, Slađana; Jevtic, Sonja; Pergal, Marija; Markovic, Aleksandar; Mutić, Jelena; Petković, Branka B.; Stanković, Dalibor

(Taylor & Francis Ltd, Abingdon, 2018)

TY  - JOUR
AU  - Vukojević, Vesna
AU  - Đurđić, Slađana
AU  - Jevtic, Sonja
AU  - Pergal, Marija
AU  - Markovic, Aleksandar
AU  - Mutić, Jelena
AU  - Petković, Branka B.
AU  - Stanković, Dalibor
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2358
AB  - In this work, the electrochemical behaviour and the subsequent development of an analytical procedure for quantification of pesticide azamethiphos, using boron-doped diamond (BDD) electrode are reported for the first time. It was found that azamethiphos electrochemical behaviour is irreversible oxidation at the potential of around 1.70 V, in 1 M nitric acid (pH 0). Also, it was found that potential of this oxidation was not pH dependent which can be attributed to the no proton involvement in electrochemical reaction on the electrode surface. The square wave voltammetric method was most appropriate for azamethiphos quantification. Under optimised experimental conditions, linear working range from 2 to 100 mu M was estimated with the detection limit of 0.45 mu M. Negligible effect of the possible interfering compound was observed. The obtained results show that the developed analytical methodology can be an adequate replacement for the, up to date, used methods for detection of organophosphorous pesticide.
PB  - Taylor & Francis Ltd, Abingdon
T2  - International Journal of Environmental Analytical Chemistry
T1  - First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach
VL  - 98
IS  - 13
SP  - 1175
EP  - 1185
DO  - 10.1080/03067319.2018.1537394
ER  - 
@article{
author = "Vukojević, Vesna and Đurđić, Slađana and Jevtic, Sonja and Pergal, Marija and Markovic, Aleksandar and Mutić, Jelena and Petković, Branka B. and Stanković, Dalibor",
year = "2018",
abstract = "In this work, the electrochemical behaviour and the subsequent development of an analytical procedure for quantification of pesticide azamethiphos, using boron-doped diamond (BDD) electrode are reported for the first time. It was found that azamethiphos electrochemical behaviour is irreversible oxidation at the potential of around 1.70 V, in 1 M nitric acid (pH 0). Also, it was found that potential of this oxidation was not pH dependent which can be attributed to the no proton involvement in electrochemical reaction on the electrode surface. The square wave voltammetric method was most appropriate for azamethiphos quantification. Under optimised experimental conditions, linear working range from 2 to 100 mu M was estimated with the detection limit of 0.45 mu M. Negligible effect of the possible interfering compound was observed. The obtained results show that the developed analytical methodology can be an adequate replacement for the, up to date, used methods for detection of organophosphorous pesticide.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "International Journal of Environmental Analytical Chemistry",
title = "First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach",
volume = "98",
number = "13",
pages = "1175-1185",
doi = "10.1080/03067319.2018.1537394"
}
Vukojević, V., Đurđić, S., Jevtic, S., Pergal, M., Markovic, A., Mutić, J., Petković, B. B.,& Stanković, D.. (2018). First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach. in International Journal of Environmental Analytical Chemistry
Taylor & Francis Ltd, Abingdon., 98(13), 1175-1185.
https://doi.org/10.1080/03067319.2018.1537394
Vukojević V, Đurđić S, Jevtic S, Pergal M, Markovic A, Mutić J, Petković BB, Stanković D. First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach. in International Journal of Environmental Analytical Chemistry. 2018;98(13):1175-1185.
doi:10.1080/03067319.2018.1537394 .
Vukojević, Vesna, Đurđić, Slađana, Jevtic, Sonja, Pergal, Marija, Markovic, Aleksandar, Mutić, Jelena, Petković, Branka B., Stanković, Dalibor, "First electrochemical investigation of organophosphorus pesticide azametiphos and its quantification using electroanalytical approach" in International Journal of Environmental Analytical Chemistry, 98, no. 13 (2018):1175-1185,
https://doi.org/10.1080/03067319.2018.1537394 . .
6
4
7

First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product

Jevtic, Sonja; Vukojević, Vesna; Đurđić, Slađana; Pergal, Marija; Manojlović, Dragan; Petković, Branka B.; Stanković, Dalibor

(Oxford : Pergamon-Elsevier Science Ltd, 2018)

TY  - JOUR
AU  - Jevtic, Sonja
AU  - Vukojević, Vesna
AU  - Đurđić, Slađana
AU  - Pergal, Marija
AU  - Manojlović, Dragan
AU  - Petković, Branka B.
AU  - Stanković, Dalibor
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2479
AB  - This work present a new approach for the detection of relatively new herbicide pethoxamid (POA), a first electrochemical behavior and determination based on its oxidation on boron-doped diamond electrode in Britton-Robinson buffer solution at pH 4. Square wave voltammetric technique was used for quantification of POA at anodic potential of 1.35 V vs reference Ag/AgCl electrode. The proposed electroanalytical method is operational in the linear working range from 3 to 100 mu M of POA with a limit of detection of 1.37 mu M. The developed analytical procedure was successfully tested for determination of this herbicide in standard/spiked river water samples and commercial herbicide Successor T SE/spiked river water samples, offering a simple, fast and inexpensive alternative way of pesticide determining to chromatographic methods employed for this purpose.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Electrochimica Acta
T1  - First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product
VL  - 277
SP  - 136
EP  - 142
DO  - 10.1016/j.electacta.2018.05.004
ER  - 
@article{
author = "Jevtic, Sonja and Vukojević, Vesna and Đurđić, Slađana and Pergal, Marija and Manojlović, Dragan and Petković, Branka B. and Stanković, Dalibor",
year = "2018",
abstract = "This work present a new approach for the detection of relatively new herbicide pethoxamid (POA), a first electrochemical behavior and determination based on its oxidation on boron-doped diamond electrode in Britton-Robinson buffer solution at pH 4. Square wave voltammetric technique was used for quantification of POA at anodic potential of 1.35 V vs reference Ag/AgCl electrode. The proposed electroanalytical method is operational in the linear working range from 3 to 100 mu M of POA with a limit of detection of 1.37 mu M. The developed analytical procedure was successfully tested for determination of this herbicide in standard/spiked river water samples and commercial herbicide Successor T SE/spiked river water samples, offering a simple, fast and inexpensive alternative way of pesticide determining to chromatographic methods employed for this purpose.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Electrochimica Acta",
title = "First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product",
volume = "277",
pages = "136-142",
doi = "10.1016/j.electacta.2018.05.004"
}
Jevtic, S., Vukojević, V., Đurđić, S., Pergal, M., Manojlović, D., Petković, B. B.,& Stanković, D.. (2018). First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product. in Electrochimica Acta
Oxford : Pergamon-Elsevier Science Ltd., 277, 136-142.
https://doi.org/10.1016/j.electacta.2018.05.004
Jevtic S, Vukojević V, Đurđić S, Pergal M, Manojlović D, Petković BB, Stanković D. First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product. in Electrochimica Acta. 2018;277:136-142.
doi:10.1016/j.electacta.2018.05.004 .
Jevtic, Sonja, Vukojević, Vesna, Đurđić, Slađana, Pergal, Marija, Manojlović, Dragan, Petković, Branka B., Stanković, Dalibor, "First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product" in Electrochimica Acta, 277 (2018):136-142,
https://doi.org/10.1016/j.electacta.2018.05.004 . .
16
8
17

Determination of Total Antioxidant Capacity in Human Milk and Infant Formula

Lugonja, Nikoleta; Stanković, Dalibor; Milić, Jelena; Spasić, Snežana; Vrvić, Miroslav

(2018)

TY  - CONF
AU  - Lugonja, Nikoleta
AU  - Stanković, Dalibor
AU  - Milić, Jelena
AU  - Spasić, Snežana
AU  - Vrvić, Miroslav
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4953
AB  - Poster presented at: 6th Workshop Specific Methods for Food Safety and Quality, 2018
T1  - Determination of Total Antioxidant Capacity in Human Milk and Infant Formula
UR  - https://hdl.handle.net/21.15107/rcub_cer_4953
ER  - 
@conference{
author = "Lugonja, Nikoleta and Stanković, Dalibor and Milić, Jelena and Spasić, Snežana and Vrvić, Miroslav",
year = "2018",
abstract = "Poster presented at: 6th Workshop Specific Methods for Food Safety and Quality, 2018",
title = "Determination of Total Antioxidant Capacity in Human Milk and Infant Formula",
url = "https://hdl.handle.net/21.15107/rcub_cer_4953"
}
Lugonja, N., Stanković, D., Milić, J., Spasić, S.,& Vrvić, M.. (2018). Determination of Total Antioxidant Capacity in Human Milk and Infant Formula. .
https://hdl.handle.net/21.15107/rcub_cer_4953
Lugonja N, Stanković D, Milić J, Spasić S, Vrvić M. Determination of Total Antioxidant Capacity in Human Milk and Infant Formula. 2018;.
https://hdl.handle.net/21.15107/rcub_cer_4953 .
Lugonja, Nikoleta, Stanković, Dalibor, Milić, Jelena, Spasić, Snežana, Vrvić, Miroslav, "Determination of Total Antioxidant Capacity in Human Milk and Infant Formula" (2018),
https://hdl.handle.net/21.15107/rcub_cer_4953 .

Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide

Pergal, Marija; Kodranov, Igor; Pergal, Miodrag M.; Dojčinović, Biljana; Stanković, Dalibor; Petković, Branka B.; Manojlović, Dragan

(Springer International Publishing Ag, Cham, 2018)

TY  - JOUR
AU  - Pergal, Marija
AU  - Kodranov, Igor
AU  - Pergal, Miodrag M.
AU  - Dojčinović, Biljana
AU  - Stanković, Dalibor
AU  - Petković, Branka B.
AU  - Manojlović, Dragan
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2424
AB  - The degradation of two sulfonylurea herbicides, nicosulfuron and thifensulfuron methyl in water by chlorine dioxide, was studied for the first time in this paper. In order to examine the optimal parameters for degradation of both herbicides, degradation was investigated under light or dark conditions with different amount of chlorine dioxide, different degradation periods, and at different pH values. Degradation efficiency of herbicides was monitored using high-performance liquid chromatography with photodiode array detection (HPLC-DAD). The degradation products were analyzed by gas chromatography with triple quadrupole mass detector (GC-QQQ). Three products were identified after degradation of nicosulfuron and two products after degradation of thifensulfuron methyl. Total organic analysis (TOC) gave insight into some differences in degradation mechanisms and degrees of mineralization after degradation of the herbicides using chlorine dioxide. A simple mechanism of herbicide degradation was proposed. Acute toxicity tests were performed on the products produced after degradation with chlorine dioxide, and the results showed that the degradation products were less toxic than the parent compounds. The findings of the present study are very useful for the treatment of wastewaters contaminated with herbicides.
PB  - Springer International Publishing Ag, Cham
T2  - Water Air and Soil Pollution
T1  - Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide
VL  - 229
IS  - 9
SP  - 287
DO  - 10.1007/s11270-018-3947-2
ER  - 
@article{
author = "Pergal, Marija and Kodranov, Igor and Pergal, Miodrag M. and Dojčinović, Biljana and Stanković, Dalibor and Petković, Branka B. and Manojlović, Dragan",
year = "2018",
abstract = "The degradation of two sulfonylurea herbicides, nicosulfuron and thifensulfuron methyl in water by chlorine dioxide, was studied for the first time in this paper. In order to examine the optimal parameters for degradation of both herbicides, degradation was investigated under light or dark conditions with different amount of chlorine dioxide, different degradation periods, and at different pH values. Degradation efficiency of herbicides was monitored using high-performance liquid chromatography with photodiode array detection (HPLC-DAD). The degradation products were analyzed by gas chromatography with triple quadrupole mass detector (GC-QQQ). Three products were identified after degradation of nicosulfuron and two products after degradation of thifensulfuron methyl. Total organic analysis (TOC) gave insight into some differences in degradation mechanisms and degrees of mineralization after degradation of the herbicides using chlorine dioxide. A simple mechanism of herbicide degradation was proposed. Acute toxicity tests were performed on the products produced after degradation with chlorine dioxide, and the results showed that the degradation products were less toxic than the parent compounds. The findings of the present study are very useful for the treatment of wastewaters contaminated with herbicides.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Water Air and Soil Pollution",
title = "Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide",
volume = "229",
number = "9",
pages = "287",
doi = "10.1007/s11270-018-3947-2"
}
Pergal, M., Kodranov, I., Pergal, M. M., Dojčinović, B., Stanković, D., Petković, B. B.,& Manojlović, D.. (2018). Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide. in Water Air and Soil Pollution
Springer International Publishing Ag, Cham., 229(9), 287.
https://doi.org/10.1007/s11270-018-3947-2
Pergal M, Kodranov I, Pergal MM, Dojčinović B, Stanković D, Petković BB, Manojlović D. Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide. in Water Air and Soil Pollution. 2018;229(9):287.
doi:10.1007/s11270-018-3947-2 .
Pergal, Marija, Kodranov, Igor, Pergal, Miodrag M., Dojčinović, Biljana, Stanković, Dalibor, Petković, Branka B., Manojlović, Dragan, "Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide" in Water Air and Soil Pollution, 229, no. 9 (2018):287,
https://doi.org/10.1007/s11270-018-3947-2 . .
1
9
4
8

Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples

Jevtic, Sonja; Stefanovic, Andela; Stanković, Dalibor; Pergal, Marija; Ivanovic, Aleksandra T.; Jokic, Anja; Petković, Branka B.

(Elsevier Science Sa, Lausanne, 2018)

TY  - JOUR
AU  - Jevtic, Sonja
AU  - Stefanovic, Andela
AU  - Stanković, Dalibor
AU  - Pergal, Marija
AU  - Ivanovic, Aleksandra T.
AU  - Jokic, Anja
AU  - Petković, Branka B.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2967
AB  - Bentazone (BZ) is selective contact-past herbicide with suspected reproductive toxicity potential for human due to possible contamination of ground and surface waters. This work presents simple, rapid, sensitive and accurate determination of bentazone at unmodified boron-doped diamond electrode, using differential pulse voltammetry in Britton-Robinson buffer (pH 4, oxidation peak at 1.0 V). Under optimized DPV conditions linear calibration curve was obtained for range of 2 to 100 mu M, with a detection limit of 0.5 mu M. The effect of possible interfering agents is negligible, confirming good selectivity of the method. The method was successfully applied to determination of bentazone in spiked river water samples. This electrochemical determination of bentazone represents a favorable alternative to other used time-consuming and expensive analytical techniques and procedures.
PB  - Elsevier Science Sa, Lausanne
T2  - Diamond and Related Materials
T1  - Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples
VL  - 81
SP  - 133
EP  - 137
DO  - 10.1016/j.diamond.2017.12.009
ER  - 
@article{
author = "Jevtic, Sonja and Stefanovic, Andela and Stanković, Dalibor and Pergal, Marija and Ivanovic, Aleksandra T. and Jokic, Anja and Petković, Branka B.",
year = "2018",
abstract = "Bentazone (BZ) is selective contact-past herbicide with suspected reproductive toxicity potential for human due to possible contamination of ground and surface waters. This work presents simple, rapid, sensitive and accurate determination of bentazone at unmodified boron-doped diamond electrode, using differential pulse voltammetry in Britton-Robinson buffer (pH 4, oxidation peak at 1.0 V). Under optimized DPV conditions linear calibration curve was obtained for range of 2 to 100 mu M, with a detection limit of 0.5 mu M. The effect of possible interfering agents is negligible, confirming good selectivity of the method. The method was successfully applied to determination of bentazone in spiked river water samples. This electrochemical determination of bentazone represents a favorable alternative to other used time-consuming and expensive analytical techniques and procedures.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Diamond and Related Materials",
title = "Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples",
volume = "81",
pages = "133-137",
doi = "10.1016/j.diamond.2017.12.009"
}
Jevtic, S., Stefanovic, A., Stanković, D., Pergal, M., Ivanovic, A. T., Jokic, A.,& Petković, B. B.. (2018). Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples. in Diamond and Related Materials
Elsevier Science Sa, Lausanne., 81, 133-137.
https://doi.org/10.1016/j.diamond.2017.12.009
Jevtic S, Stefanovic A, Stanković D, Pergal M, Ivanovic AT, Jokic A, Petković BB. Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples. in Diamond and Related Materials. 2018;81:133-137.
doi:10.1016/j.diamond.2017.12.009 .
Jevtic, Sonja, Stefanovic, Andela, Stanković, Dalibor, Pergal, Marija, Ivanovic, Aleksandra T., Jokic, Anja, Petković, Branka B., "Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples" in Diamond and Related Materials, 81 (2018):133-137,
https://doi.org/10.1016/j.diamond.2017.12.009 . .
37
25
38

Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples

Jevtic, Sonja; Stefanovic, Andela; Stanković, Dalibor; Pergal, Marija; Ivanovic, Aleksandra T.; Jokic, Anja; Petković, Branka B.

(Elsevier Science Sa, Lausanne, 2018)

TY  - JOUR
AU  - Jevtic, Sonja
AU  - Stefanovic, Andela
AU  - Stanković, Dalibor
AU  - Pergal, Marija
AU  - Ivanovic, Aleksandra T.
AU  - Jokic, Anja
AU  - Petković, Branka B.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2470
AB  - Bentazone (BZ) is selective contact-past herbicide with suspected reproductive toxicity potential for human due to possible contamination of ground and surface waters. This work presents simple, rapid, sensitive and accurate determination of bentazone at unmodified boron-doped diamond electrode, using differential pulse voltammetry in Britton-Robinson buffer (pH 4, oxidation peak at 1.0 V). Under optimized DPV conditions linear calibration curve was obtained for range of 2 to 100 mu M, with a detection limit of 0.5 mu M. The effect of possible interfering agents is negligible, confirming good selectivity of the method. The method was successfully applied to determination of bentazone in spiked river water samples. This electrochemical determination of bentazone represents a favorable alternative to other used time-consuming and expensive analytical techniques and procedures.
PB  - Elsevier Science Sa, Lausanne
T2  - Diamond and Related Materials
T1  - Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples
VL  - 81
SP  - 133
EP  - 137
DO  - 10.1016/j.diamond.2017.12.009
ER  - 
@article{
author = "Jevtic, Sonja and Stefanovic, Andela and Stanković, Dalibor and Pergal, Marija and Ivanovic, Aleksandra T. and Jokic, Anja and Petković, Branka B.",
year = "2018",
abstract = "Bentazone (BZ) is selective contact-past herbicide with suspected reproductive toxicity potential for human due to possible contamination of ground and surface waters. This work presents simple, rapid, sensitive and accurate determination of bentazone at unmodified boron-doped diamond electrode, using differential pulse voltammetry in Britton-Robinson buffer (pH 4, oxidation peak at 1.0 V). Under optimized DPV conditions linear calibration curve was obtained for range of 2 to 100 mu M, with a detection limit of 0.5 mu M. The effect of possible interfering agents is negligible, confirming good selectivity of the method. The method was successfully applied to determination of bentazone in spiked river water samples. This electrochemical determination of bentazone represents a favorable alternative to other used time-consuming and expensive analytical techniques and procedures.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Diamond and Related Materials",
title = "Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples",
volume = "81",
pages = "133-137",
doi = "10.1016/j.diamond.2017.12.009"
}
Jevtic, S., Stefanovic, A., Stanković, D., Pergal, M., Ivanovic, A. T., Jokic, A.,& Petković, B. B.. (2018). Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples. in Diamond and Related Materials
Elsevier Science Sa, Lausanne., 81, 133-137.
https://doi.org/10.1016/j.diamond.2017.12.009
Jevtic S, Stefanovic A, Stanković D, Pergal M, Ivanovic AT, Jokic A, Petković BB. Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples. in Diamond and Related Materials. 2018;81:133-137.
doi:10.1016/j.diamond.2017.12.009 .
Jevtic, Sonja, Stefanovic, Andela, Stanković, Dalibor, Pergal, Marija, Ivanovic, Aleksandra T., Jokic, Anja, Petković, Branka B., "Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples" in Diamond and Related Materials, 81 (2018):133-137,
https://doi.org/10.1016/j.diamond.2017.12.009 . .
37
25
38