Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach
Само за регистроване кориснике
2019
Аутори
Stanković, DaliborOgnjanović, Miloš
Espinosa, Ana
del Puerto Morales, Maria
Bessais, Lotfi
Zehani, Karim
Antić, Bratislav
Dojčinović, Biljana
Чланак у часопису (Објављена верзија)
,
Springer
Метаподаци
Приказ свих података о документуАпстракт
In this study, for the first time, we developed a novel platform for the removal of the synthetic organic dye Reactive Blue 52 based on a screen-printed electrode (SPCE). Additionally, SPCE was supported on a nanocomposite obtained by decoration of reduced graphene oxide (RGO) with iron oxide nanoflowers (IONFs), labeled as IONF@RGO/SPCE. IONFs were synthesized by polyol-mediated reduction of iron (III) chloride and characterized. Nanocomposite was prepared using a microwave hydrothermal-assisted procedure. The high stability (service life) of the IONF@RGO/SPCE electrode was measured, and it remained almost unchanged over time, achieving the same removal efficiency after 50 cycles of usage. Electrical impedance spectroscopy (EIS) tests indicated the synergetic effect of the used IONF@RGO by reducing resistivity of the system and improving its catalytic activity, which was confirmed with cyclic voltammetry (CV tests) where the great increase of the electrochemically active surface area ...sites was obvious. The results clearly indicate that with this approach, the optimum removal time of the selected pollutant was only 30 min, at a working potential of 3 V and with potassium chloride as the supporting electrolyte, with color removal efficiency of 99%, while chemical oxygen demand (COD) of more than 40%, total organic carbon (TOC) decrease of around 20%, and biochemical oxygen demand (BOD5), i.e., biodegradability (BOD5/COD ratio) significantly increased were measured after only 1 h of the treatment. Overall, the electrochemical removal procedure proposed in this study could be a reliable novel system, opening a new approach to using screen print–based electrodes.
Кључне речи:
Electrochemical removal system / Reactive Blue 52 / Iron oxide nanoflowers / Graphene oxideИзвор:
Electrocatalysis, 2019, 10, 6, 663-671Издавач:
- Springer Science and Business Media LLC
Финансирање / пројекти:
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-FP7-621375)
- Spanish Ministerio de Ciencia, Innovación y Universidades (MAT2017-88148-R)
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Магнетни и радионуклидима обележени наноструктурни материјали за примене у медицини (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45015)
DOI: 10.1007/s12678-019-00554-1
ISSN: 1868-2529; 1868-5994
WoS: 000492662400008
Scopus: 2-s2.0-85071233008
Институција/група
IHTMTY - JOUR AU - Stanković, Dalibor AU - Ognjanović, Miloš AU - Espinosa, Ana AU - del Puerto Morales, Maria AU - Bessais, Lotfi AU - Zehani, Karim AU - Antić, Bratislav AU - Dojčinović, Biljana PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3250 AB - In this study, for the first time, we developed a novel platform for the removal of the synthetic organic dye Reactive Blue 52 based on a screen-printed electrode (SPCE). Additionally, SPCE was supported on a nanocomposite obtained by decoration of reduced graphene oxide (RGO) with iron oxide nanoflowers (IONFs), labeled as IONF@RGO/SPCE. IONFs were synthesized by polyol-mediated reduction of iron (III) chloride and characterized. Nanocomposite was prepared using a microwave hydrothermal-assisted procedure. The high stability (service life) of the IONF@RGO/SPCE electrode was measured, and it remained almost unchanged over time, achieving the same removal efficiency after 50 cycles of usage. Electrical impedance spectroscopy (EIS) tests indicated the synergetic effect of the used IONF@RGO by reducing resistivity of the system and improving its catalytic activity, which was confirmed with cyclic voltammetry (CV tests) where the great increase of the electrochemically active surface area sites was obvious. The results clearly indicate that with this approach, the optimum removal time of the selected pollutant was only 30 min, at a working potential of 3 V and with potassium chloride as the supporting electrolyte, with color removal efficiency of 99%, while chemical oxygen demand (COD) of more than 40%, total organic carbon (TOC) decrease of around 20%, and biochemical oxygen demand (BOD5), i.e., biodegradability (BOD5/COD ratio) significantly increased were measured after only 1 h of the treatment. Overall, the electrochemical removal procedure proposed in this study could be a reliable novel system, opening a new approach to using screen print–based electrodes. PB - Springer Science and Business Media LLC T2 - Electrocatalysis T1 - Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach VL - 10 IS - 6 SP - 663 EP - 671 DO - 10.1007/s12678-019-00554-1 ER -
@article{ author = "Stanković, Dalibor and Ognjanović, Miloš and Espinosa, Ana and del Puerto Morales, Maria and Bessais, Lotfi and Zehani, Karim and Antić, Bratislav and Dojčinović, Biljana", year = "2019", abstract = "In this study, for the first time, we developed a novel platform for the removal of the synthetic organic dye Reactive Blue 52 based on a screen-printed electrode (SPCE). Additionally, SPCE was supported on a nanocomposite obtained by decoration of reduced graphene oxide (RGO) with iron oxide nanoflowers (IONFs), labeled as IONF@RGO/SPCE. IONFs were synthesized by polyol-mediated reduction of iron (III) chloride and characterized. Nanocomposite was prepared using a microwave hydrothermal-assisted procedure. The high stability (service life) of the IONF@RGO/SPCE electrode was measured, and it remained almost unchanged over time, achieving the same removal efficiency after 50 cycles of usage. Electrical impedance spectroscopy (EIS) tests indicated the synergetic effect of the used IONF@RGO by reducing resistivity of the system and improving its catalytic activity, which was confirmed with cyclic voltammetry (CV tests) where the great increase of the electrochemically active surface area sites was obvious. The results clearly indicate that with this approach, the optimum removal time of the selected pollutant was only 30 min, at a working potential of 3 V and with potassium chloride as the supporting electrolyte, with color removal efficiency of 99%, while chemical oxygen demand (COD) of more than 40%, total organic carbon (TOC) decrease of around 20%, and biochemical oxygen demand (BOD5), i.e., biodegradability (BOD5/COD ratio) significantly increased were measured after only 1 h of the treatment. Overall, the electrochemical removal procedure proposed in this study could be a reliable novel system, opening a new approach to using screen print–based electrodes.", publisher = "Springer Science and Business Media LLC", journal = "Electrocatalysis", title = "Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach", volume = "10", number = "6", pages = "663-671", doi = "10.1007/s12678-019-00554-1" }
Stanković, D., Ognjanović, M., Espinosa, A., del Puerto Morales, M., Bessais, L., Zehani, K., Antić, B.,& Dojčinović, B.. (2019). Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach. in Electrocatalysis Springer Science and Business Media LLC., 10(6), 663-671. https://doi.org/10.1007/s12678-019-00554-1
Stanković D, Ognjanović M, Espinosa A, del Puerto Morales M, Bessais L, Zehani K, Antić B, Dojčinović B. Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach. in Electrocatalysis. 2019;10(6):663-671. doi:10.1007/s12678-019-00554-1 .
Stanković, Dalibor, Ognjanović, Miloš, Espinosa, Ana, del Puerto Morales, Maria, Bessais, Lotfi, Zehani, Karim, Antić, Bratislav, Dojčinović, Biljana, "Iron Oxide Nanoflower–Based Screen Print Electrode for Enhancement Removal of Organic Dye Using Electrochemical Approach" in Electrocatalysis, 10, no. 6 (2019):663-671, https://doi.org/10.1007/s12678-019-00554-1 . .