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Ferrous ion induced decomposition of alkyl hypochlorites
(Elsevier, 1981)
The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76%. In decomposition of tertiary alkyl ...
Activation of aluminium in chloride containing solutions
(Elsevier, 1988)
Galvanostatic transients were recorded for anodic dissolution of high purity aluminium in neutral chloride solutions. All transients, except at very low current densities (below 50 μA cm-2), are characterized by an overshoot ...
Some aspects of current density distribution in electrolytic cells I: Dendritic growth of cadmium at the cathode edge in galvanostatic electrodeposition
(Elsevier, 1983)
The equivalent electrical resistance of a cell with plane parallel electrodes is described by a simple mathematical model. The limits of this model were determined experimentally. The relation between the overpotential at ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Rise time of silicon p-i-n photodiodes
(Elsevier, 1983)
Exact analytical expressions are derived for the short circuit photodiode currents excited by light pulses, under the assumption that the drift carrier velocity linearly depends on the electric field in the depletion layer. ...
Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone
(Wiley, 1981)
Unambiguous signal assignments in the 13C spectra of monodeuterated cyclooctanones derived from the lead tetraacetate or silver oxide/bromine oxidations of the corresponding 1‐monodeutero‐alcohols have been obtained from ...
Multistage alkaline permanganate degradation of a type-III kerogen
(Elsevier, 1985)
In order to obtain evidence on the relationship between kerogen structural types and the quantity and nature of their oxidation products, the products of a multistage (13 step) alkaline permanganate degradation of type-III ...
Mass spectrometric analysis of the carbon content in the plasma of a horizontal electric arc burning in a graphite tube / Massenspektrometrische Analyse des Kohlenstoffgehaltes im Plasma einer horizontalen Bogenentladung in einem Graphitrohr
(Springer Science and Business Media LLC, 1981)
The carbon content in the plasma of a horizontal electric arc in a graphite tube, burning in air, in the presence of an inhomogeneous magnetic field has been determined. The modifications with one and two rotating arc ...
Synthesis, structure, and reactions of secosteroids containing a medium-sized ring. Part 17. Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 3-tosylates
(Royal Society of Chemistry, 1980)
Kinetic measurements of the solvolysis of (Z)-3α- and (Z)-3β-, and (E)-3α- and (E)-3β-tosyloxy-5,10-secocholest-1(10)-en-5-ones in buffered aqueous acetone (90 : 10 v/v) reveal that the (Z)-3α-, (E)-3α-, and (E)-3β-tosylates ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...