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Structural effects in electrocatalysis: Oxygen and hydrogen peroxide reduction on single crystal gold electrodes and the effects of lead ad-atoms
(Elsevier, 1982)
Structural effects in electrocatalysis have been clearly and definitely demonstrated for example in the oxidation of HCOOH, CH3OH and CH2O on platinum single crystal electrodes. In this note, we report considerable structural ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Electrocatalysis of hydrogen evolution on polycrystalline palladium by rhodium nanoislands in alkaline solution
(Elsevier, 2015)
Hydrogen evolution reaction (HER) was investigated on bimetallic Rh/Pd(poly) electrodes in alkaline solution. Bimetallic electrodes were obtained by a spontaneous deposition of rhodium on polycrystalline Pd. Characterization ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
Catalytic activities of Pt thin films electrodeposited onto Bi coated glassy carbon substrate toward formic acid electrooxidation
(Elsevier, 2014)
Formic acid oxidation was studied on platinum-coated bismuth deposits on glassy carbon substrate. The catalyst was prepared by a two-step process using chronocoulometry, i.e. controlled amount of Bi was electrodeposited ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part II. Applications
(Elsevier, 1987)
The criteria obtained for a new reaction scheme of O2 reduction have been applied to experimental data from several laboratories. The possibilities and merits of a new scheme have been analysed. Some results, not fully ...
Electrosorption of hydrogen and sulphuric acid anions on single-crystal platinum stepped surfaces. Part I. The [110] zone
(Elsevier, 1988)
The adsorption of hydrogen and sulphuric acid anions has been studied on single-crystal platinum stepped surfaces from the [110] zone. Both processes depend on the orientation of the electrode surface. The multiple states ...