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Electrocatalysis on Surfaces Modified by Foreign Metal Adatoms
(WILEY‐VCH, 1979)
An approach to the problem of electrocatalysis, which consists of modification of electrode surfaces by foreign metal adatoms, is presented. The paper reviews the work done in the author's lab on the effects of foreign ...
The critical overpotential for zinc dendrite formation
(Kluwer Academic Publishers, 1979)
The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popov et al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there ...
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Mass spectrometric analysis of plasma composition of a D. C. arc burning in an air atmosphere / Massenspektrometrische Analyse der Plasmazusammensetzung eines Gleichstrombogens in Luft
(Springer-Verlag, 1979)
The plasma composition of a d. c. arc burning in air was investigated by mass spectrometry. It has been found that the CO and CO2 contents result from homogenous chemical reactions and that the content of carbon is about ...
Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 5-p-nitrobenzoates
(Pergamon Press, 1979)
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and ...
Reflectance study of cation adsorption on oxide layers of gold and platinum electrodes
(Elsevier Sequoia S.A., Lausanne, 1979)
The dissolution of iron under cathodic polarization
(Pergamon Press, 1979)
It has been shown that the dissolution rate for iron at cathodic potential is higher than expected on the grounds of the Wagner-Traud mixed potential theory. This observation cannot be explained by a parallel chemical ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...