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The reaction of lead tetra-acetate with some acyclic hydroxy-ethers
(Elsevier, 1966)
By means of lead tetra-acetate in refluxing benzene open-chain 1,2-, 1,3-, 1,4- and 1,5-hydroxy-ethers are mainly converted to the corresponding five-membered or six-membered cylic products. Thus, 2-alkoxy-1-ethanols afford ...
Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids
(Elsevier, 1966)
Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied ...
Lead tetra-acetate oxidation of saturated aliphatic alcohols-V. Factors influencing the formation of cyclic ethers and carbonyl compounds
(Elsevier, 1966)
Factors influencing the relative rates of the homolytic and heterolytic processes in the lead tetra-acetate oxidation of unbranched primary and secondary aliphatic alcohols have been investigated, with a view to determine ...