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Electrocatalytic optimization of faradaic yields in the chlorate cell process
(Elsevier, 1984)
It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well ...
Fundamental aspects of pulsating current metal electrodeposition VIII: The effect of pause-to-pulse ratio on microthrowing power of metal deposition
(Elsevier, 1984)
The effect of a pulsating current on the microthrowing power of metal deposits in the early stage of deposition was investigated by scanning electron microscopy. It is shown that at the same average current density the ...
Determination of low levels of cyanide with a silver/silver sulphide wire electrode
(Elsevier, 1987)
A silver/silver sulphide electrode is prepred quickly by holding a cleaned silver wire in vapours from molten sulphur. In 1000-10 mg l-1 cyanide solutions, the electrode exhibits a linear E/log CCN function which becomes ...
Structural effects in electrocatalysis
(Springer Science and Business Media LLC, 1982)
Studies of chemical reactions on well-defined surfaces provide fundamental data on surface reactivity and guidelines for the understanding and design of catalytic materials but few such studies have been done in electrocatalysis. ...
Configurations in unsymmetrically N-methyl-N-substituted 2-phenylacetamides
(Elsevier, 1986)
The syntheses of a various N-methyl-N-substituted 2-phenylacetamides of the general formula PhCH 2 CON(CH 3 )R, wherein, R is ethyl, n-propyl, isopropyl and t-butyl group, were performed. The 1 H n.m.r. spectra of these ...
Kerogen structural studies-oxidations with alkaline permanganate and with ferric chloride
(Elsevier, 1980)
Two oxidizing agents were used for structural studies of the kerogen from Aleksinac shale (Yugoslavia), namely: (1) alkaline potassium permanganate, and (2) acidic ferric chloride. (1) The main goal with alkaline permanganate ...
Two‐dimensional NMR spectra of sesquiterpenes. I—NOESY study of caryophyllenes from Inula spiraeifolia
(John Wiley & Sons Ltd., 1987)
The application of two‐dimensional NOE NMR spectroscopy (NOESY) for the stereochemical assignment of isomeric 14‐acetoxy‐13‐hydroxy‐ and 13‐acetoxy‐14‐hydroxy‐5,6‐caryophyllen‐7‐ones, and their acetylation products, is ...
The behaviour of mixed metal sulphide/silver suphide sensing materials in solutions of silver ions
(Analytica Chimica Acta, 1985)
Hydrophobized graphite electrodes activated with CuS/Ag2S can be used to measure silver ion activities as effectively as silver sulphide electrodes, whereas electrodes activatd with PbS/Ag2S or CdS/Ag2S are useless for ...
Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium
(Royal Society of Chemistry, 1985)
The reaction-field theory based on dipole and quadrupole interactions has been generalized, yielding an expression for the energy as a function of point dipole and quadrupole position and orientation within a spherical ...
Optical and electrochemical study of underpotential deposition of bismuth on gold electrode
(Elsevier, 1980)
The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with ...