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Determination of low levels of cyanide with a silver/silver sulphide wire electrode

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1987
Authors
Jovanović, Vladislava M.
Sak-Bosnar, Milan
Jovanovć, Momir S.
Article (Published version)
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Abstract
A silver/silver sulphide electrode is prepred quickly by holding a cleaned silver wire in vapours from molten sulphur. In 1000-10 mg l-1 cyanide solutions, the electrode exhibits a linear E/log CCN function which becomes slightly sinusoidal for 10-0.1 mg l-1 cyanide. The average slope is slightl super-Nerstian (10 mV/decade concentration). The applicability of the electrode is demonstrated for the determinations of microgram quantities of water-soluble cyanide from the Prussian blue pigments which are constituents of externally applied cosmetics. The home-made electrode provides results agreing with those obtained with commercially available electrodes.
Keywords:
silver electrode / silver sulphide electrode / determinations of water-soluble cyanide
Source:
Analytica Chimica Acta, 1987, 196, C, 221-227
Publisher:
  • Elsevier

DOI: 10.1016/S0003-2670(00)83087-1

ISSN: 0003-2670

Scopus: 2-s2.0-0342634434
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14
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/3662
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IHTM

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