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Two‐dimensional NMR spectra of sesquiterpenes. I—NOESY study of caryophyllenes from Inula spiraeifolia
(John Wiley & Sons Ltd., 1987)
The application of two‐dimensional NOE NMR spectroscopy (NOESY) for the stereochemical assignment of isomeric 14‐acetoxy‐13‐hydroxy‐ and 13‐acetoxy‐14‐hydroxy‐5,6‐caryophyllen‐7‐ones, and their acetylation products, is ...
The behaviour of mixed metal sulphide/silver suphide sensing materials in solutions of silver ions
(Analytica Chimica Acta, 1985)
Hydrophobized graphite electrodes activated with CuS/Ag2S can be used to measure silver ion activities as effectively as silver sulphide electrodes, whereas electrodes activatd with PbS/Ag2S or CdS/Ag2S are useless for ...
Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium
(Royal Society of Chemistry, 1985)
The reaction-field theory based on dipole and quadrupole interactions has been generalized, yielding an expression for the energy as a function of point dipole and quadrupole position and orientation within a spherical ...
Optical and electrochemical study of underpotential deposition of bismuth on gold electrode
(Elsevier, 1980)
The underpotential deposition of Bi on Au has been investigated by specular reflectance spectroscopy and linear sweep voltammetry. The spectral dependance of ΔR/R caused by Bi adatoms has been determined and compared with ...
The effect of anions on the electrochemical behaviour of aluminium
(Elsevier, 1983)
Aluminum has been known to exhibit widely different electrochemical properties in different aqueous electrolytes. Thus, OH- ions in strongly alkaline solutions reveal its strong affinity to water by dissolving its protective ...
Fundamental aspects of plating technology I: The determination of the optimum deposition current density
(Elsevier, 1983)
It is shown that the optimum plating overpotential or the optimum current density is determined by the upper limit of validity of the Tafel relationship for the deposition process.
Combined lyotropic and thermotropic phase transitions of deoxycholic acid
(Elsevier, 1980)
Phase transitions of deoxycholic acid have been examined by studying systems which form a clathrate during crystallization. It has been shown that, depending upon the type of solvent molecule present, the deoxycholic acid ...
Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds
(Elsevier, 1985)
The influence of the copper content in CuxCo3-xO4 (0 ≫ × ≫ 1) mixed oxides on carbon monoxide oxidation in the presence of SO2 was investigated. The average oxidation rate was found to increase very slowly with increasing ...
Surface properties of RuO2 + IrO2 mixed oxide electrodes
(Elsevier, 1986)
The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV ...
Structural effects in electrocatalysis: oxidation of formic acid and hydrogen adsorption on platinum single-crystal stepped surfaces
(Elsevier, 1986)
The oxidation of formic acid and hydrogen adsorption have been measured on platinum single-crystal stepped surfaces with five orientations. A pronounced structural sensitivity of both reactions has been found. They show a ...